Low-Temperature Heat Capacities and Standard Molar Enthalpy of Formation of Gramine (C_(11)H_(14)N_2)
文献类型：期刊论文
| 作者 | Chen Jingtao2; Kong Yuxia3; Di Youying3; Yang Weiwei3; Tan Zhicheng1 |
| 刊名 | Chinese Journal of Chemistry
 |
| 出版日期 | 2011-01-01 |
| 卷号 | 29期号:11页码:2278 |
| ISSN号 | 1001-604X |
| 英文摘要 | Low-temperature heat capacities of gramine (C_(11)H_(14)N_2) were measured by a precision automated adiabatic calorimeter over the temperature range from 78 to 401 K. A polynomial equation of heat capacities as a function of temperature was fitted by least squares method. Based on the fitted polynomial, the smoothed heat capacities and thermodynamic functions of the compound relative to the standard reference temperature 298.15 K were calculated and tabulated at 5 K intervals. The constant-volume energy of combustion of the compound at T=298.15 K was measured by a precision oxygen-bomb combustion calorimeter as Δ_cU/=―(35336.7±13.9) J?g~(-1). The standard molar enthalpy of combustion of the compound was determined to be Δ_CH~Θ_m =―(6163.2±2.4) kJ?mol~(-1), according to the definition of combustion enthalpy. Finally, the standard molar enthalpy of formation of the compound was calculated to be Δ_CH~Θ_m =―(166.2±2.8) kJ?mol~(-1) in accordance with Hess law. |
| 语种 | 英语 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/174252]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.中国科学院大连化学物理研究所 2.Department of Chemistry and Chemical Engineering, Shaanxi Institute of Education 3.聊城大学 |
| 推荐引用方式 GB/T 7714 | Chen Jingtao,Kong Yuxia,Di Youying,et al. Low-Temperature Heat Capacities and Standard Molar Enthalpy of Formation of Gramine (C_(11)H_(14)N_2)[J]. Chinese Journal of Chemistry,2011,29(11):2278. |
| APA | Chen Jingtao,Kong Yuxia,Di Youying,Yang Weiwei,&Tan Zhicheng.(2011).Low-Temperature Heat Capacities and Standard Molar Enthalpy of Formation of Gramine (C_(11)H_(14)N_2).Chinese Journal of Chemistry,29(11),2278. |
| MLA | Chen Jingtao,et al."Low-Temperature Heat Capacities and Standard Molar Enthalpy of Formation of Gramine (C_(11)H_(14)N_2)".Chinese Journal of Chemistry 29.11(2011):2278. |
入库方式： OAI收割
来源：大连化学物理研究所
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