synthesischaracterizationandphasetransformationof3dopenframeworkzincphosphatezn6h2op5o20c5n2h14c6h16n2053h2o
文献类型：期刊论文
| 作者 | SONG Yu2; DONG Zhaojun2; WANG Yongwei1; FU Jun2; LI Jiyang2 |
| 刊名 | chemicalresearchinchineseuniversities
 |
| 出版日期 | 2009-01-01 |
| 卷号 | 000期号:004页码:407 |
| ISSN号 | 1005-9040 |
| 英文摘要 | With N,N′-dimethylpiperazine（DMPIP） as the structure-directing agent, a zinc phosphate Zn6（H2O）P5O20 C5N2H14 C6H16N20.5·3H2O（1） with a novel three-dimensional（3D） open-framework architecture was hydrothermally synthesized. Its structure was determined by single-crystal X-ray diffraction analysis and further characterized by ICP, NMR, and TG analyses. Compound 1 crystallized in the triclinic space group P1（No.2） with a=0.9984（2） nm, b=1.2354（3） nm, c=1.2384（3） nm, α=88.32（3）°, β=74.57（3）°, γ=75.81（3）° and Z=2. The alternation arrrangement of tetrahedral Zn unitsZnO4 and ZnO3（H2O） and PO4 units forms an anionic 3D open framework containing intersecting 16-, 10- and 8-ring channels. Water molecules, diprotonated DMPIP, and diprotonated N-methyl-piperazine（MPIP） decomposed from DMPIP, are located in the channels and interact with the host framework via H-bonds. Compound 1 transforms to another new phase（compound 2） upon calcination at 200―350℃ with the removal of the water coordinated to Zn atoms in the lattice. The phase transformation of compound 2 was further studied. |
| 语种 | 英语 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/174269]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.中国科学院大连化学物理研究所 2.吉林大学 |
| 推荐引用方式 GB/T 7714 | SONG Yu,DONG Zhaojun,WANG Yongwei,et al. synthesischaracterizationandphasetransformationof3dopenframeworkzincphosphatezn6h2op5o20c5n2h14c6h16n2053h2o[J]. chemicalresearchinchineseuniversities,2009,000(004):407. |
| APA | SONG Yu,DONG Zhaojun,WANG Yongwei,FU Jun,&LI Jiyang.(2009).synthesischaracterizationandphasetransformationof3dopenframeworkzincphosphatezn6h2op5o20c5n2h14c6h16n2053h2o.chemicalresearchinchineseuniversities,000(004),407. |
| MLA | SONG Yu,et al."synthesischaracterizationandphasetransformationof3dopenframeworkzincphosphatezn6h2op5o20c5n2h14c6h16n2053h2o".chemicalresearchinchineseuniversities 000.004(2009):407. |
入库方式： OAI收割
来源：大连化学物理研究所
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