synthesesstructuralcharacterizationsandspectroscopicpropertiesoftwocoppericomplexesbasedondiphosphineligandsand23fpyrazino110phenanthroline
文献类型：期刊论文
| 作者 | Lu YanLei4; Zhu Ning4; Zhao YuMeng4; Lin Sen4; Kuang XiaoNan4; Li ZhongFeng4; Xin XiuLan2; Yang YuPing3; Jin QiongHua4; Zhang JiangWei1 |
| 刊名 | chinesejournalofinorganicchemistry
 |
| 出版日期 | 2019-01-01 |
| 卷号 | 35期号:4页码:720 |
| ISSN号 | 1001-4861 |
| 英文摘要 | Two novel copper(I) complexes Cu(dppBz)(dpq)ClO4 (1) and Cu(dppe)(dpq)ClO4 (2) (dppBz=1,2-bis (diphenylphosphino)benzene, dppe=1,2-bis(diphenylphosphino)ethene, dpq=2,3-fpyrazino1,10phenanthroline) have been synthesized and characterized by X-ray diffraction, elemental analysis, infrared spectroscopy, absorption spectra, luminescent spectra, 11-1 NMR, 31P NMR spectroscopy and terahertz (THz) time-domain absorption spectroscopy. The central Cu(I) ion is chelated by a diimine ligand and a diphosphine ligand forming a distorted tetrahedron configuration for 1, and the configuration of 2 is similar to 1. The luminescent spectra of 2 indicated that the emission has metal-to-ligand charge transfer (MLCT) characteristics. The terahertz time-domain absorption spectroscopy analysis in a range of 0.2-2.8 THz showed that the absorption peaks at 0.40-0.90 THz are related to the coordination of the central Cu(I). CCDC: 1874580, 1; 1874581, 2. |
| 语种 | 英语 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/174885]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.中国科学院大连化学物理研究所 2.陕西省地震局 3.中国科学院 4.中国科学院福建物质结构研究所 |
| 推荐引用方式 GB/T 7714 | Lu YanLei,Zhu Ning,Zhao YuMeng,et al. synthesesstructuralcharacterizationsandspectroscopicpropertiesoftwocoppericomplexesbasedondiphosphineligandsand23fpyrazino110phenanthroline[J]. chinesejournalofinorganicchemistry,2019,35(4):720. |
| APA | Lu YanLei.,Zhu Ning.,Zhao YuMeng.,Lin Sen.,Kuang XiaoNan.,...&Zhang JiangWei.(2019).synthesesstructuralcharacterizationsandspectroscopicpropertiesoftwocoppericomplexesbasedondiphosphineligandsand23fpyrazino110phenanthroline.chinesejournalofinorganicchemistry,35(4),720. |
| MLA | Lu YanLei,et al."synthesesstructuralcharacterizationsandspectroscopicpropertiesoftwocoppericomplexesbasedondiphosphineligandsand23fpyrazino110phenanthroline".chinesejournalofinorganicchemistry 35.4(2019):720. |
入库方式： OAI收割
来源：大连化学物理研究所
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