Activation and Spillover of Hydrogen on Sub-1nm Palladium Nanoclusters Confined within Sodalite Zeolite for the Semi-Hydrogenation of Alkynes
文献类型：期刊论文
| 作者 | Wang, Shuai2; Zhao, Zhi-Jian2; Chang, Xin2; Zhao, Jiubing2; Tian, Hao2; Yang, Chengsheng2; Li, Mingrun1; Fu, Qiang1; Mu, Rentao2; Gong, Jinlong2 |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2019-06-03 |
| 卷号 | 58期号:23页码:7668-7672 |
| ISSN号 | 1433-7851 |
| 关键词 | encapsulated catalysts ethylene hydrogen spillover semi-hydrogenation zeolites |
| DOI | 10.1002/anie.201903827 |
| 通讯作者 | Mu, Rentao(murt@tju.edu.cn) ; Gong, Jinlong(jlgong@tju.edu.cn) |
| 英文摘要 | The search for efficient nontoxic catalysts able to perform industrial hydrogenations is a topic of interest, with relevance to many catalytic processes. Herein, we describe a mechanistic phenomenon for the activation and spillover of hydrogen for remarkable selectivity in the semi-hydrogenation of acetylene over sub-1nm Pd nanoclusters confined within sodalite (SOD) zeolite (Pd@SOD). Specifically, hydrogen is dissociated on the Pd nanoclusters to form hydrogen species (i.e., hydrogen atoms and hydroxyl groups) that spill over the SOD surfaces. The design and utilization of the small-pore zeolite SOD (six-membered rings with 0.28x0.28nm channels) is crucial as it only allows H-2 diffusion into the channels to reach the encapsulated Pd nanoclusters and thus avoids over-hydrogenation to form ethane. Pd@SOD exhibits an ethylene selectivity of over 94.5%, while that of conventional Pd/SOD is approximately 21.5%. |
| WOS关键词 | SELECTIVE HYDROGENATION ; SUBSURFACE CARBON ; METAL-CLUSTERS ; PARTICLE-SIZE ; CATALYSTS ; PD ; NANOPARTICLES ; CONSEQUENCES ; REACTIVITY ; ETHYNE |
| 资助项目 | National Natural Science Foundation of China[21525626] ; National Natural Science Foundation of China[21676181] ; National Natural Science Foundation of China[91645106] ; Program of Introducing Talents of Discipline to Universities[B06006] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| WOS记录号 | WOS:000474804800018 |
| 资助机构 | National Natural Science Foundation of China ; National Natural Science Foundation of China ; Program of Introducing Talents of Discipline to Universities ; Program of Introducing Talents of Discipline to Universities ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Program of Introducing Talents of Discipline to Universities ; Program of Introducing Talents of Discipline to Universities ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Program of Introducing Talents of Discipline to Universities ; Program of Introducing Talents of Discipline to Universities ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Program of Introducing Talents of Discipline to Universities ; Program of Introducing Talents of Discipline to Universities |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/175077]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Mu, Rentao; Gong, Jinlong |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Collaborat Innovat Ctr Chem Energy Mat iChEM, Dalian 116023, Peoples R China 2.Tianjin Univ, Key Lab Green Chem Technol, Minist Educ, Sch Chem Engn & Technol,Collaborat Innovat Ctr Ch, Weijin Rd 92, Tianjin 300072, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Shuai,Zhao, Zhi-Jian,Chang, Xin,et al. Activation and Spillover of Hydrogen on Sub-1nm Palladium Nanoclusters Confined within Sodalite Zeolite for the Semi-Hydrogenation of Alkynes[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2019,58(23):7668-7672. |
| APA | Wang, Shuai.,Zhao, Zhi-Jian.,Chang, Xin.,Zhao, Jiubing.,Tian, Hao.,...&Gong, Jinlong.(2019).Activation and Spillover of Hydrogen on Sub-1nm Palladium Nanoclusters Confined within Sodalite Zeolite for the Semi-Hydrogenation of Alkynes.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,58(23),7668-7672. |
| MLA | Wang, Shuai,et al."Activation and Spillover of Hydrogen on Sub-1nm Palladium Nanoclusters Confined within Sodalite Zeolite for the Semi-Hydrogenation of Alkynes".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 58.23(2019):7668-7672. |
入库方式： OAI收割
来源：大连化学物理研究所
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