Catalytic furfural hydrogenation to furfuryl alcohol over Cu/SiO2 catalysts: A comparative study of the preparation methods
文献类型：期刊论文
| 作者 | Du, Hong2; Ma, Xiuyun2; Yan, Peifang2; Jiang, Miao2; Zhao, Ziang2,3; Zhang, Z. Conrad1,2 |
| 刊名 | FUEL PROCESSING TECHNOLOGY
 |
| 出版日期 | 2019-10-01 |
| 卷号 | 193页码:221-231 |
| 关键词 | Cu/SiO2 catalyst Preparation methods Furfural Furfuryl alcohol Gas phase |
| ISSN号 | 0378-3820 |
| DOI | 10.1016/j.fuproc.2019.05.003 |
| 通讯作者 | Zhang, Z. Conrad(zczhang@yahoo.com) |
| 英文摘要 | Furfuryl alcohol, a vital intermediate for the production of foundry resins, fragrances, pharmaceuticals and pesticide, is produced by hydrogenation of furfural in gas phase or liquid phase. The furfuryl alcohol production in gas phase over silica supported copper catalyst is favored thanks to the environmental and technical advantages. The effect of preparation methods of silica supported copper catalysts on the structure and performance was investigated by means of ICP, N-2 physisorption, ex-situ/in-situ XRD, in-situ XPS, FT-1R, H-2-TPR, TEM, N20 titration, TG as well as furfural hydrogenation. The results indicated that the different catalyst synthesis strategies led to the diverse copper species in the calcined samples and disparate Cu-0 surface area as well as different molar ratio of Cu+/(Cu+ + Cu-0) in the fresh samples. The performance of impregnation derived sample was poorer than that of commercial CuCr-Strem catalyst. The catalysts prepared by deposition precipitation and ion exchange exhibited similar performance to the CuCr-Strem. The ammonia evaporation derived catalyst (Cu/SiO2-EA) showed superior performance in the activity, selectivity and stability among all the studied catalysts. The excellent performance was related to the highest surface area of Cu-0, smallest copper particle size, large surface area and pore volume as well as appropriate higher Cu+/(Cu+ + Cu-0) ratio. Furthermore, all the copper catalysts went through deactivation, which was caused by carbon deposition, during the reaction. Owing to the largest amount of Cu-0 sites and large S-BET, the Cu/SiO2-EA exhibited the slowest deactivation rate. |
| WOS关键词 | VAPOR-PHASE HYDROGENATION ; SELECTIVE HYDROGENATION ; HIGHLY EFFICIENT ; METHYL ACETATE ; CU-CATALYSTS ; DIMETHYL OXALATE ; BIOMASS ; ACID ; PERFORMANCE ; STABILITY |
| 资助项目 | National Natural Science Foundation of China[21808217] ; Dalian Institute of Chemical Physics[DICP ZZBS201812] |
| WOS研究方向 | Chemistry ; Energy & Fuels ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000473842100024 |
| 出版者 | ELSEVIER SCIENCE BV |
| 资助机构 | National Natural Science Foundation of China ; National Natural Science Foundation of China ; Dalian Institute of Chemical Physics ; Dalian Institute of Chemical Physics ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Dalian Institute of Chemical Physics ; Dalian Institute of Chemical Physics ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Dalian Institute of Chemical Physics ; Dalian Institute of Chemical Physics ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Dalian Institute of Chemical Physics ; Dalian Institute of Chemical Physics |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/175425]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Zhang, Z. Conrad |
| 作者单位 | 1.Chinese Acad Sci, State Key Lab Catalysis, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Dalian Natl Lab Clean Energy, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Du, Hong,Ma, Xiuyun,Yan, Peifang,et al. Catalytic furfural hydrogenation to furfuryl alcohol over Cu/SiO2 catalysts: A comparative study of the preparation methods[J]. FUEL PROCESSING TECHNOLOGY,2019,193:221-231. |
| APA | Du, Hong,Ma, Xiuyun,Yan, Peifang,Jiang, Miao,Zhao, Ziang,&Zhang, Z. Conrad.(2019).Catalytic furfural hydrogenation to furfuryl alcohol over Cu/SiO2 catalysts: A comparative study of the preparation methods.FUEL PROCESSING TECHNOLOGY,193,221-231. |
| MLA | Du, Hong,et al."Catalytic furfural hydrogenation to furfuryl alcohol over Cu/SiO2 catalysts: A comparative study of the preparation methods".FUEL PROCESSING TECHNOLOGY 193(2019):221-231. |
入库方式： OAI收割
来源：大连化学物理研究所
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