Ceria nanocube with reactive {100} exposure planes: Simple and controllable synthesis under moderate conditions
文献类型：期刊论文
| 作者 | Wang, Yao1,2; Su, Hong-Jiu1; Wang, Shu-Dong1 |
| 刊名 | CERAMICS INTERNATIONAL
 |
| 出版日期 | 2019-08-15 |
| 卷号 | 45期号:12页码:15199-15204 |
| ISSN号 | 0272-8842 |
| 关键词 | Ceria Nanocubes Ce4+ ions CH3COO- ions {100} planes |
| DOI | 10.1016/j.ceramint.2019.05.004 |
| 通讯作者 | Su, Hong-Jiu(suhj@dicp.ac.cn) ; Wang, Shu-Dong(wangsd@dicp.ac.cn) |
| 英文摘要 | {100} planes of CeO2 are unstable polar surfaces and important to enhance the oxygen storage capacity. However, a convenient method is still needed for the synthesis of ceria nanocubes which expose six {100} facets. Here, a new and facile synthesis strategy has been developed to synthesize single-crystalline nanocubes of CeO2. According to transmission electron microscopy, these nanocubes are enclosed by six {100} facets. It is proved that in the synthesis process, the acetate radical ions would adsorb on the positive charged Ce(OH)(3) formed from the reaction of Ce3+ and ammonia, then partially inhibit the redox between Ce(OH)(3) and NO3- and protect the {100} facets during crystal growth. Meanwhile, the Ce4+ ions would act as crystal seeds to facilitate the formation of single crystals. Both of the addition of Ce4+ ions and CH3COO- ions are necessary for the synthesis of monocrystal ceria nanocubes. Throughout the synthesis process, it is moderate reaction conditions that the pressure is atmospheric pressure and temperature is no higher than 80 degrees C. |
| WOS关键词 | CEO2 NANOCUBES ; NANOPARTICLES ; NANOCRYSTALS ; NANOSTRUCTURES ; MORPHOLOGY ; CEO2(111) ; CHEMISTRY ; OXIDATION ; CO2 |
| 资助项目 | Youth Innovation Promotion Association of CAS |
| WOS研究方向 | Materials Science |
| 语种 | 英语 |
| 出版者 | ELSEVIER SCI LTD |
| WOS记录号 | WOS:000474322000087 |
| 资助机构 | Youth Innovation Promotion Association of CAS ; Youth Innovation Promotion Association of CAS ; Youth Innovation Promotion Association of CAS ; Youth Innovation Promotion Association of CAS ; Youth Innovation Promotion Association of CAS ; Youth Innovation Promotion Association of CAS ; Youth Innovation Promotion Association of CAS ; Youth Innovation Promotion Association of CAS |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/175526]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Su, Hong-Jiu; Wang, Shu-Dong |
| 作者单位 | 1.Chinese Acad Sci, Dalian Natl Lab Clean Energy, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Yao,Su, Hong-Jiu,Wang, Shu-Dong. Ceria nanocube with reactive {100} exposure planes: Simple and controllable synthesis under moderate conditions[J]. CERAMICS INTERNATIONAL,2019,45(12):15199-15204. |
| APA | Wang, Yao,Su, Hong-Jiu,&Wang, Shu-Dong.(2019).Ceria nanocube with reactive {100} exposure planes: Simple and controllable synthesis under moderate conditions.CERAMICS INTERNATIONAL,45(12),15199-15204. |
| MLA | Wang, Yao,et al."Ceria nanocube with reactive {100} exposure planes: Simple and controllable synthesis under moderate conditions".CERAMICS INTERNATIONAL 45.12(2019):15199-15204. |
入库方式： OAI收割
来源：大连化学物理研究所
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