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The Evolution in Catalytic Activity Driven by Periodic Transformation in the Inner Sites of Gold Clusters

文献类型：期刊论文

作者Sun, Yongnan1; Wang, Endong2; Ren, Yujing3; Xiao, Kang4; Liu, Xu1; Yang, Dan1; Gao, Yi2; Ding, Weiping1; Zhu, Yan1
刊名ADVANCED FUNCTIONAL MATERIALS
出版日期2019-07-11
页码8
ISSN号1616-301X
关键词activity evolution gold clusters inner sites periodic structure
DOI10.1002/adfm.201904242
通讯作者Gao, Yi(gaoyi@sinap.ac.cn) ; Zhu, Yan(zhuyan@nju.edu.cn)
英文摘要It is extremely difficult to distinguish the contributions of different sites on the surface and in the inner sites of a catalyst to the overall catalytic performance, as the observed catalytic results reflect an ensemble average from almost all the active sites. How do the inner sites of a catalyst that seem to be not directly involved in a catalytic process exactly contribute to the catalytic performance? Toward this goal, herein the studies not only provide fundamental insights into how the alteration of Au8n+4(SR)(4n+8) clusters by only the inner structure can dramatically change the intrinsic catalytic properties, where Au8n+4(SR)(4n+8) (n = 3, 4, 5) clusters have the same surface motifs but share a periodic kernel structure, but also further demonstrate that the evolution in catalytic activity can potentially be determined by periodic transformation in the inner kernels.
WOS关键词BONDING PROPERTIES ; CO OXIDATION ; NANOCLUSTERS ; TEMPERATURE ; ALKYNES ; COMPLEXES ; LIGANDS ; SN
资助项目National Natural Science Foundation of China[21773109] ; National Natural Science Foundation of China[21773287] ; National Natural Science Foundation of China[91845104] ; Fundamental Research Funds for the Central Universities
WOS研究方向Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
语种英语
出版者WILEY-V C H VERLAG GMBH
WOS记录号WOS:000474959000001
资助机构National Natural Science Foundation of China ; National Natural Science Foundation of China ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities
源URL[http://cas-ir.dicp.ac.cn/handle/321008/175605]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者Gao, Yi; Zhu, Yan
作者单位1.Nanjing Univ, Sch Chem & Chem Engn, Nanjing 210093, Jiangsu, Peoples R China
2.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
4.Nanjing Univ Posts & Telecommun, Sch Mat Sci & Engn, Nanjing 210023, Jiangsu, Peoples R China
推荐引用方式
GB/T 7714		 Sun, Yongnan,Wang, Endong,Ren, Yujing,et al. The Evolution in Catalytic Activity Driven by Periodic Transformation in the Inner Sites of Gold Clusters[J]. ADVANCED FUNCTIONAL MATERIALS,2019:8.
APA Sun, Yongnan.,Wang, Endong.,Ren, Yujing.,Xiao, Kang.,Liu, Xu.,...&Zhu, Yan.(2019).The Evolution in Catalytic Activity Driven by Periodic Transformation in the Inner Sites of Gold Clusters.ADVANCED FUNCTIONAL MATERIALS,8.
MLA Sun, Yongnan,et al."The Evolution in Catalytic Activity Driven by Periodic Transformation in the Inner Sites of Gold Clusters".ADVANCED FUNCTIONAL MATERIALS (2019):8.

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来源：大连化学物理研究所

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