The catalytic activity of alkali metal alkoxides and titanium alkoxides in the hydrosilylation of unfunctionalized olefins
文献类型：期刊论文
| 作者 | Yang, Xiaoling1; Bai, Ying1; Li, Jiayun1; Liu, Yu1; Peng, Jiajian1; Li, Tianbo2; Lang, Rui2; Qiao, Botao2 |
| 刊名 | PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
 |
| 出版日期 | 2019 |
| 卷号 | 194期号:1-2页码:83-86 |
| 关键词 | Hydrosilylation titanium alkoxide alkali metal alkoxide olefin |
| ISSN号 | 1042-6507 |
| DOI | 10.1080/10426507.2018.1493480 |
| 通讯作者 | Bai, Ying(ybai@hznu.edu.cn) ; Peng, Jiajian(jjpeng@hznu.edu.cn) |
| 英文摘要 | The catalytic activities of titanium alkoxides and alkali metal alkoxides for hydrosilylation of unfunctionalized olefins have been studied. Titanium(IV) alkoxides showed excellent catalytic activity, while alkali metal alkoxides have low catalytic activity for the hydrosilylation of olefins. However, by using titanocene dichloride as an additive, alkali metal alkoxides showed also excellent catalytic property for hydrosilylation. In comparison with titanium alkoxides, no -adduct was obtained by using alkali metal alkoxides/Cp2TiCl2 as catalysts. |
| WOS关键词 | ALKENE HYDROSILYLATION ; COMPLEXES ; IRON ; REDUCTION |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000469421300012 |
| 出版者 | TAYLOR & FRANCIS LTD |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/175874]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Bai, Ying; Peng, Jiajian |
| 作者单位 | 1.Hangzhou Normal Univ, Key Lab Organosilicon Chem & Mat Technol, Minist Educ, Hangzhou 311121, Zhejiang, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Xiaoling,Bai, Ying,Li, Jiayun,et al. The catalytic activity of alkali metal alkoxides and titanium alkoxides in the hydrosilylation of unfunctionalized olefins[J]. PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS,2019,194(1-2):83-86. |
| APA | Yang, Xiaoling.,Bai, Ying.,Li, Jiayun.,Liu, Yu.,Peng, Jiajian.,...&Qiao, Botao.(2019).The catalytic activity of alkali metal alkoxides and titanium alkoxides in the hydrosilylation of unfunctionalized olefins.PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS,194(1-2),83-86. |
| MLA | Yang, Xiaoling,et al."The catalytic activity of alkali metal alkoxides and titanium alkoxides in the hydrosilylation of unfunctionalized olefins".PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS 194.1-2(2019):83-86. |
入库方式： OAI收割
来源：大连化学物理研究所
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