Supramolecular topology design of silver(I) and copper(II) coordination polymers through a new semi-rigid sulfonyl ligand with different anion templates
文献类型：期刊论文
| 作者 | Qi, Zhaoxian1,2; Zhao, Li1; Li, Zhiwen2,3; Tian, Shanli2; Xiao, Qian1; Deng, Yuheng1; Zhang, Jiangwei2; Li, Gao2; Wan, Chongqing1 |
| 刊名 | DALTON TRANSACTIONS
 |
| 出版日期 | 2019-05-28 |
| 卷号 | 48期号:20页码:6730-6737 |
| ISSN号 | 1477-9226 |
| DOI | 10.1039/c9dt00257j |
| 通讯作者 | Zhang, Jiangwei(jwzhang@dicp.ac.cn) |
| 英文摘要 | A series of metal organic coordination polymers (MOCPs) of silver(I) and copper(II) coordinated with a novel multifunctional semi-rigid sulfonyl ligand with different anion templates and oxidation states were designed for the first time. In addition, their atomically precise molecular structure was determined by single crystal X-ray diffraction analysis. In comparison, the topology of silver(I)-based MOCPs is affected significantly by different anion templates. The coordination modes are quite different with the anions varying: linear for ClO4-, trilateral for CO2CF3-, and tetrahedral for CO2C2F5-. Due to the difference of electron configurations between Ag(I) and Cu(II), the coordinated configuration of the metal center is also different. While the coordinated configuration of Cu(II) center tends to be placed in an octahedron. Furthermore, for the copper(II) MOCPs, the oxidation state of the L ligand also plays an important role. When the N atoms in L were oxidized, the coordination mode of Cu(II) became tetrahedral with Cu(II) stuck on the bottom of the conventional octahedral mode. In general, it is an effective and controllable strategy to mediate the coordination mode and aggregation of supramolecular assembly-based MOCPs through the combination of a multifunctional organic ligand and its corresponding oxidation state design; elaborate metallic species and electron configuration selection; and suitable anion template introduction to generate multiform and hierarchical non-covalent bond interactions including pi-pi interactions and hydrogen bond formation that afford their coordination mode diversity. |
| WOS关键词 | COMPLEXES ; LUMINESCENCE ; FRAMEWORKS |
| 资助项目 | National Natural Science Foundation of China[21371123] ; National Natural Science Foundation of China[21701168] ; Liaoning Natural Science Foundation[20170540897] ; Liaoning Natural Science Foundation[20180510050] ; Natural Science Foundation of Beijing Municipality[2172014] ; State Key Laboratory of Structural Chemistry at Fujian Institute of Research on the Structure of Matter[20160009] ; Key Laboratory of Life Organic Phosphorus Chemistry and Chemical Biology, Ministry of Education, Tsinghua University |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| 出版者 | ROYAL SOC CHEMISTRY |
| WOS记录号 | WOS:000472452900042 |
| 资助机构 | National Natural Science Foundation of China ; National Natural Science Foundation of China ; Liaoning Natural Science Foundation ; Liaoning Natural Science Foundation ; Natural Science Foundation of Beijing Municipality ; Natural Science Foundation of Beijing Municipality ; State Key Laboratory of Structural Chemistry at Fujian Institute of Research on the Structure of Matter ; State Key Laboratory of Structural Chemistry at Fujian Institute of Research on the Structure of Matter ; Key Laboratory of Life Organic Phosphorus Chemistry and Chemical Biology, Ministry of Education, Tsinghua University ; Key Laboratory of Life Organic Phosphorus Chemistry and Chemical Biology, Ministry of Education, Tsinghua University ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Liaoning Natural Science Foundation ; Liaoning Natural Science Foundation ; Natural Science Foundation of Beijing Municipality ; Natural Science Foundation of Beijing Municipality ; State Key Laboratory of Structural Chemistry at Fujian Institute of Research on the Structure of Matter ; State Key Laboratory of Structural Chemistry at Fujian Institute of Research on the Structure of Matter ; Key Laboratory of Life Organic Phosphorus Chemistry and Chemical Biology, Ministry of Education, Tsinghua University ; Key Laboratory of Life Organic Phosphorus Chemistry and Chemical Biology, Ministry of Education, Tsinghua University ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Liaoning Natural Science Foundation ; Liaoning Natural Science Foundation ; Natural Science Foundation of Beijing Municipality ; Natural Science Foundation of Beijing Municipality ; State Key Laboratory of Structural Chemistry at Fujian Institute of Research on the Structure of Matter ; State Key Laboratory of Structural Chemistry at Fujian Institute of Research on the Structure of Matter ; Key Laboratory of Life Organic Phosphorus Chemistry and Chemical Biology, Ministry of Education, Tsinghua University ; Key Laboratory of Life Organic Phosphorus Chemistry and Chemical Biology, Ministry of Education, Tsinghua University ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Liaoning Natural Science Foundation ; Liaoning Natural Science Foundation ; Natural Science Foundation of Beijing Municipality ; Natural Science Foundation of Beijing Municipality ; State Key Laboratory of Structural Chemistry at Fujian Institute of Research on the Structure of Matter ; State Key Laboratory of Structural Chemistry at Fujian Institute of Research on the Structure of Matter ; Key Laboratory of Life Organic Phosphorus Chemistry and Chemical Biology, Ministry of Education, Tsinghua University ; Key Laboratory of Life Organic Phosphorus Chemistry and Chemical Biology, Ministry of Education, Tsinghua University |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/176012]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Zhang, Jiangwei |
| 作者单位 | 1.Capital Normal Univ, Dept Chem, Beijing Key Lab Opt Mat & Photon Devices, Beijing 100048, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 3.Liaoning Normal Univ, Dept Chem & Chem Engn, Dalian 116029, Peoples R China |
| 推荐引用方式 GB/T 7714 | Qi, Zhaoxian,Zhao, Li,Li, Zhiwen,et al. Supramolecular topology design of silver(I) and copper(II) coordination polymers through a new semi-rigid sulfonyl ligand with different anion templates[J]. DALTON TRANSACTIONS,2019,48(20):6730-6737. |
| APA | Qi, Zhaoxian.,Zhao, Li.,Li, Zhiwen.,Tian, Shanli.,Xiao, Qian.,...&Wan, Chongqing.(2019).Supramolecular topology design of silver(I) and copper(II) coordination polymers through a new semi-rigid sulfonyl ligand with different anion templates.DALTON TRANSACTIONS,48(20),6730-6737. |
| MLA | Qi, Zhaoxian,et al."Supramolecular topology design of silver(I) and copper(II) coordination polymers through a new semi-rigid sulfonyl ligand with different anion templates".DALTON TRANSACTIONS 48.20(2019):6730-6737. |
入库方式： OAI收割
来源：大连化学物理研究所
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