Synthesis of Open-Cage [60]Fullerenes with Five Carbonyl Groups on the Rim of the 15-Membered Orifice
文献类型：期刊论文
| 作者 | Xu, Dan1; Yang, Dazhi1; Su, Jie1; Gan, Liangbing1,2 |
| 刊名 | CHEMPLUSCHEM
 |
| 出版日期 | 2019-06-01 |
| 卷号 | 84期号:6页码:608-612 |
| 关键词 | alcoholysis aromatization fullerenes iminofuranones open-cage compounds |
| ISSN号 | 2192-6506 |
| DOI | 10.1002/cplu.201900017 |
| 通讯作者 | Su, Jie(jie.su@pku.edu.cn) ; Gan, Liangbing(gan@pku.edu.cn) |
| 英文摘要 | A new type of open-cage [60]fullerene was prepared starting from our previously reported open-cage [60]fullerenes containing hydroxy and tert-butylperoxo groups, and an iminofuranone moiety on the rim of the orifice. The key reactions are alcoholysis with MeOH/PCl5 and reductive aromatization with SnCl2 or HI (aq). The resulting open-cage compound contains two ketone carbonyls, two amide carbonyls, and one ester carbonyl group. The X-ray crystal structure of the precursor compound shows that the 18-membered orifice is almost completely blocked because of the presence of the amide group directly above the orifice. |
| WOS关键词 | SKELETON BONDS ; FULLERENE ; C-60 ; DERIVATIVES ; CLEAVAGE |
| 资助项目 | NNSFC[21672009] ; NNSFC[21871015] ; MOST[2015CB856600] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000470922000007 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 资助机构 | NNSFC ; NNSFC ; MOST ; MOST ; NNSFC ; NNSFC ; MOST ; MOST ; NNSFC ; NNSFC ; MOST ; MOST ; NNSFC ; NNSFC ; MOST ; MOST |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/176051]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Su, Jie; Gan, Liangbing |
| 作者单位 | 1.Peking Univ, Coll Chem & Mol Engn, Key Lab Bioorgan Chem & Mol Engn, Beijing Natl Lab Mol Sci,Minist Educ, Beijing 100871, Peoples R China 2.Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, Dan,Yang, Dazhi,Su, Jie,et al. Synthesis of Open-Cage [60]Fullerenes with Five Carbonyl Groups on the Rim of the 15-Membered Orifice[J]. CHEMPLUSCHEM,2019,84(6):608-612. |
| APA | Xu, Dan,Yang, Dazhi,Su, Jie,&Gan, Liangbing.(2019).Synthesis of Open-Cage [60]Fullerenes with Five Carbonyl Groups on the Rim of the 15-Membered Orifice.CHEMPLUSCHEM,84(6),608-612. |
| MLA | Xu, Dan,et al."Synthesis of Open-Cage [60]Fullerenes with Five Carbonyl Groups on the Rim of the 15-Membered Orifice".CHEMPLUSCHEM 84.6(2019):608-612. |
入库方式： OAI收割
来源：大连化学物理研究所
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