ahighperformancenonnoblemetalelectrocatalystfortheoxygenreductionreactionderivedfromametalorganicframework
文献类型：期刊论文
| 作者 | Bai Yangzhi2; Yi Baolian2; Li Jia1; Jiang Shangfeng2 ; Zhang Hongjie2; Shao Zhigang2; Song Yujiang1
|
| 刊名 | 催化学报
 |
| 出版日期 | 2016-01-01 |
| 卷号 | 37期号:7页码:1127 |
| ISSN号 | 0253-9837 |
| 英文摘要 | The development of a non-precious metal electrocatalyst (NPME) with a performance superior to commercial Pt/C for the oxygen reduction reaction (ORR) is important for the commercialization of fuel cells. We report the synthesis of a NPME by heat-treating Co-based metal organic frameworks (ZIF-67) with a small average size of 44 nm. The electrocatalyst pyrolyzed at 600 degrees C showed the best performance and the performance was enhanced when it was supported on BP 2000. The resulting electrocatalyst was composed of 10 nm Co nanoparticles coated by 3-12 layers of N doped graphite layers which as a whole was embedded in a carbon matrix. The ORR performance of the electrocatalyst was tested by rotating disk electrode tests in O-2-saturated 0.1 mol/L KOH under ambient conditions. The electrocatalyst (1.0 mg/cm(2)) showed an onset potential of 1.017 V (vs. RHE) and a half-wave potential of 0.857 V (vs. RHE), which showed it was as good as the commercial Pt/C (20 mu gpt/cm(2)). Furthermore, the electrocatalyst possessed much better stability and resistance to methanol crossover than Pt/C. (C) 2016, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved. |
| 资助项目 | [National Basic Research Program of China (973 Program)] ; [National Natural Science Foundation of China] |
| 语种 | 英语 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/176479]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.大连理工大学 2.中国科学院大连化学物理研究所 |
| 推荐引用方式 GB/T 7714 | Bai Yangzhi,Yi Baolian,Li Jia,et al. ahighperformancenonnoblemetalelectrocatalystfortheoxygenreductionreactionderivedfromametalorganicframework[J]. 催化学报,2016,37(7):1127. |
| APA | Bai Yangzhi.,Yi Baolian.,Li Jia.,Jiang Shangfeng.,Zhang Hongjie.,...&Song Yujiang.(2016).ahighperformancenonnoblemetalelectrocatalystfortheoxygenreductionreactionderivedfromametalorganicframework.催化学报,37(7),1127. |
| MLA | Bai Yangzhi,et al."ahighperformancenonnoblemetalelectrocatalystfortheoxygenreductionreactionderivedfromametalorganicframework".催化学报 37.7(2016):1127. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。