chemoselectivehydrogenolysisoftetrahydrofurfurylalcoholto15pentanedioloverirmooxsio2catalyst
文献类型：期刊论文
| 作者 | Wang Zhiqiang2; Pholjaroen Boonrat2; Li Mengxia2; Dong Wenjun1; Li Ning2; Wang Aiqin2; Wang Xiaodong2; Cong Yu2; Zhang Tao2 |
| 刊名 | journalofenergychemistry
 |
| 出版日期 | 2014-01-01 |
| 卷号 | 23期号:4页码:427 |
| ISSN号 | 2095-4956 |
| 英文摘要 | In this work, MoO x promoted Ir 2 catalysts were prepared and used for the selective hydrogenolysis of tetrahydrofurfuryl alcohol (THFA) to 1,5-pentanediol in a continuous flow reactor. The effects of different noble metals (Ir, Pt, Pd, Ru, Rh), supports and Ir contents were screened. Among the investigated catalysts, 4 wt%Ir-MoO x 2 with a Mo x species attached on them is essential for the excellent catalytic performance of Ir-MoO x 2 . The catalyst exhibited a better hydrogenolysis efficiency of THFA with the selectivity of 1,5-pentanediol of 65%–74% at a conversion of THFA of 70%–75% when the initial THFA concentration is ranging from 20 wt% and 40 wt%. And higher system pressure was also in favor of the conversion of THFA. During a stability test, the conversion of THFA and 1,5-pentanediol yield over Ir-MoO x 2 decreased with reaction time, which can be explained by the leaching of Mo species during the reaction. |
| 语种 | 英语 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/177146]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.浙江理工大学 2.中国科学院大连化学物理研究所 |
| 推荐引用方式 GB/T 7714 | Wang Zhiqiang,Pholjaroen Boonrat,Li Mengxia,et al. chemoselectivehydrogenolysisoftetrahydrofurfurylalcoholto15pentanedioloverirmooxsio2catalyst[J]. journalofenergychemistry,2014,23(4):427. |
| APA | Wang Zhiqiang.,Pholjaroen Boonrat.,Li Mengxia.,Dong Wenjun.,Li Ning.,...&Zhang Tao.(2014).chemoselectivehydrogenolysisoftetrahydrofurfurylalcoholto15pentanedioloverirmooxsio2catalyst.journalofenergychemistry,23(4),427. |
| MLA | Wang Zhiqiang,et al."chemoselectivehydrogenolysisoftetrahydrofurfurylalcoholto15pentanedioloverirmooxsio2catalyst".journalofenergychemistry 23.4(2014):427. |
入库方式： OAI收割
来源：大连化学物理研究所
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