synthesischaracterizationandluminescentpropertiesoftwocoppericomplexesbasedon22biquinolineandphosphorousligand
文献类型：期刊论文
| 作者 | Sun Lingzhi3; Wang Yu3; Lin Sen3; Liu Jianming2; Li Zhongfeng3; Zhang Jiangwei1; Jin Qionghua3 |
| 刊名 | chinesejournalofstructuralchemistry
 |
| 出版日期 | 2018-01-01 |
| 卷号 | 37期号:8页码:1313 |
| ISSN号 | 0254-5861 |
| 英文摘要 | Three new copper(I) complexes, namely Cu(DPEphos)(Biq)CF3SO3 (1) and Cu(PPh3)(2)(Biq)CF3SO3 (2) and Cu(PPh3)(2)(Biq)ClO4(3) (DPEphos = bis 2-(diphenylphosp hino)phenylether, PPh3 = triphenylphosphine and Biq = 2,2'-biquinoline), are synthesized and characterized by IR, H-1 NMR, P-31 NMR, fluorescence spectra and terahertz time-domain spectroscopy (THz-TDS). Complex 1 crystallizes in triclinic, space group P (1) over bar with a = 12.6997(5), b = 13.2813(5), c = 15.3593(6) angstrom, alpha = 80.211(3)degrees, beta= 88.752(3)degrees, gamma = 70.113(3)degrees, V = 2398.85(15) angstrom(3), C55H41.2CUF3N2O2,M-r = 1018.27, Z = 2, D-c = 1.410 g/cm(3), F(000) = 1048, mu = 0.628 mm(-1), the final R = 0.0450 and wR = 0.1105 for 9419 observed reflections (I > 2 sigma(I)). Complex 2 crystallizes in monoclinic, space group C2/c with a = 19.9961(7), b = 15.9774(5), c = 17.7908(6) angstrom, beta = 119.758(4)degrees, V = 4982.8(3) angstrom(3), C56.47H47.88CuF3N2O4.47P2S, Mr = 1040.54, Z = 4, D-c = 1.387 g/cm(3), F(000) = 2154, mu = 0.606 mm(-1), the final R = 0.0430 and wR = 0.1218 for 4897 observed reflections (I > 2 sigma(I)). Complex 3 crystallizes in monoclinic, space group C2/c with a = 19.7534(8), b = 15.0797(5), c = 17.8097(7) angstrom, beta = 116.400(5)degrees, V = 4751.8(3) angstrom(3), C-56 H(45)C1CuN(3)O(4)P(2), M-r= 984.88, Z = 4, D-c= 1.377 g/cm(3), F(000) = 2040, mu = 0.635 mm(-1), the final R = 0.0731 and wR = 0.2180 for 4670 observed reflections (I > 2 sigma(I)). In the emission spectra, shifts of emission peak are derived from ligand-centered (pi-pi*) transition. |
| 资助项目 | [National Natural Science Foundation of China] ; [Beijing Municipal Natural Science Foundation] |
| 语种 | 英语 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/177581]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.中国科学院大连化学物理研究所 2.北京大学 3.首都师范大学 |
| 推荐引用方式 GB/T 7714 | Sun Lingzhi,Wang Yu,Lin Sen,et al. synthesischaracterizationandluminescentpropertiesoftwocoppericomplexesbasedon22biquinolineandphosphorousligand[J]. chinesejournalofstructuralchemistry,2018,37(8):1313. |
| APA | Sun Lingzhi.,Wang Yu.,Lin Sen.,Liu Jianming.,Li Zhongfeng.,...&Jin Qionghua.(2018).synthesischaracterizationandluminescentpropertiesoftwocoppericomplexesbasedon22biquinolineandphosphorousligand.chinesejournalofstructuralchemistry,37(8),1313. |
| MLA | Sun Lingzhi,et al."synthesischaracterizationandluminescentpropertiesoftwocoppericomplexesbasedon22biquinolineandphosphorousligand".chinesejournalofstructuralchemistry 37.8(2018):1313. |
入库方式： OAI收割
来源：大连化学物理研究所
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