asilicaimmobilizedpt2catalystfortheselectiveaerobicoxidationofmethaneviaanelectrontransferchain
文献类型：期刊论文
| 作者 | Zengjian An; Xiulian Pan; Xiumei Liu; Xiuwen Han; Xinhe Bao |
| 刊名 | journalofnaturalgaschemistry
 |
| 出版日期 | 2008-01-01 |
| 卷号 | 17期号:2页码:120 |
| ISSN号 | 1003-9953 |
| 英文摘要 | The combination of Pt2+, benzoquinone and NaNO2 forms an electron-transfer chain, which leads to the oxidation of methane by O-2 in CF3COOH aqueous solution. The overall turnover number per hour (TOF) of methane at 120 degrees C is 0.5 h(-1), however, only about one fourth (23%) of methane is converted to the desired product of methanol in the formation of CF3COOCH3. The over-oxidation of methane to CO2, over the catalyst with the Pt2+ species immobilized via 2,2'-bipyridyl as a ligand on the silica substrate, is depressed distinctly. Under the same conditions, the conversion to methanol dominates, and no CO2 is observed, on account of the over-oxidation of methane, as confirmed by the isotope experiment. |
| 语种 | 英语 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/177884]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 中国科学院大连化学物理研究所 |
| 推荐引用方式 GB/T 7714 | Zengjian An,Xiulian Pan,Xiumei Liu,et al. asilicaimmobilizedpt2catalystfortheselectiveaerobicoxidationofmethaneviaanelectrontransferchain[J]. journalofnaturalgaschemistry,2008,17(2):120. |
| APA | Zengjian An,Xiulian Pan,Xiumei Liu,Xiuwen Han,&Xinhe Bao.(2008).asilicaimmobilizedpt2catalystfortheselectiveaerobicoxidationofmethaneviaanelectrontransferchain.journalofnaturalgaschemistry,17(2),120. |
| MLA | Zengjian An,et al."asilicaimmobilizedpt2catalystfortheselectiveaerobicoxidationofmethaneviaanelectrontransferchain".journalofnaturalgaschemistry 17.2(2008):120. |
入库方式： OAI收割
来源：大连化学物理研究所
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