rhodiumiiicatalyzed32annulativecouplingbetweenoximesandelectrondeficientalkynes
文献类型：期刊论文
| 作者 | Zhou Xukai; Yu Songjie; Qi Zisong; Li Xingwei |
| 刊名 | sciencechinachemistry
 |
| 出版日期 | 2015-01-01 |
| 卷号 | 58期号:8页码:1297 |
| ISSN号 | 1674-7291 |
| 英文摘要 | Rhodium(III)-catalyzed coupling between ketoximes and alkynes via C–H activation and annulation typically followed the 4+2 selectivity to afford isoquinolines. By designing alkynes bearing a highly electron-withdrawing group and under substrate control, we have successfully switched the selectivity of the coupling between oximes and alkynes to the alternative 3+2 annulation, leading to the efficient synthesis of indenamines. This process features good regioselectivity for both substrates, high efficiency, broad substrate scope, and excellent functional group tolerance. |
| 语种 | 英语 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/178192]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 中国科学院大连化学物理研究所 |
| 推荐引用方式 GB/T 7714 | Zhou Xukai,Yu Songjie,Qi Zisong,et al. rhodiumiiicatalyzed32annulativecouplingbetweenoximesandelectrondeficientalkynes[J]. sciencechinachemistry,2015,58(8):1297. |
| APA | Zhou Xukai,Yu Songjie,Qi Zisong,&Li Xingwei.(2015).rhodiumiiicatalyzed32annulativecouplingbetweenoximesandelectrondeficientalkynes.sciencechinachemistry,58(8),1297. |
| MLA | Zhou Xukai,et al."rhodiumiiicatalyzed32annulativecouplingbetweenoximesandelectrondeficientalkynes".sciencechinachemistry 58.8(2015):1297. |
入库方式： OAI收割
来源：大连化学物理研究所
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