Direct conversion of fructose-based carbohydrates to 5-ethoxymethylfurfural catalyzed by AlCl_3·6H_2O/BF_3·(Et)_2O in ethanol
文献类型：期刊论文
| 作者 | Jia Xiuquan; Ma Jiping; Che Penghua; Lu Fang; Miao Hong; Gao Jin; Xu Jie |
| 刊名 | Journal of Energy Chemistry
 |
| 出版日期 | 2013-01-01 |
| 卷号 | 22期号:1页码:93 |
| ISSN号 | 2095-4956 |
| 英文摘要 | Direct conversion of fructose-based carbohydrates to 5-ethoxymethylfurfural (EMF) catalyzed by Lewis acid in ethanol was investigated. It was found that BF 3 ·(Et) 2 O was favorable for 5-hydroxymethylfurfural (HMF) etherification to EMF. BF 3 ·(Et) 2 O combination with AlCl 3 ·6H 2 O with the molar ratio of 1 was an effective catalyst system for synthesis of EMF from fructose-based carbohydrates. 55.0%, 45.4% and 23.9% of EMF yields were obtained from fructose, inulin and sucrose under optimized conditions, respectively. |
| 语种 | 英语 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/178518]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 中国科学院大连化学物理研究所 |
| 推荐引用方式 GB/T 7714 | Jia Xiuquan,Ma Jiping,Che Penghua,et al. Direct conversion of fructose-based carbohydrates to 5-ethoxymethylfurfural catalyzed by AlCl_3·6H_2O/BF_3·(Et)_2O in ethanol[J]. Journal of Energy Chemistry,2013,22(1):93. |
| APA | Jia Xiuquan.,Ma Jiping.,Che Penghua.,Lu Fang.,Miao Hong.,...&Xu Jie.(2013).Direct conversion of fructose-based carbohydrates to 5-ethoxymethylfurfural catalyzed by AlCl_3·6H_2O/BF_3·(Et)_2O in ethanol.Journal of Energy Chemistry,22(1),93. |
| MLA | Jia Xiuquan,et al."Direct conversion of fructose-based carbohydrates to 5-ethoxymethylfurfural catalyzed by AlCl_3·6H_2O/BF_3·(Et)_2O in ethanol".Journal of Energy Chemistry 22.1(2013):93. |
入库方式： OAI收割
来源：大连化学物理研究所
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