Ni0.33Co0.67MoS4 nanosheets as a bifunctional electrolytic water catalyst for overall water splitting
文献类型：期刊论文
| 作者 | Hang, Lifeng1,3; Zhang, Tao1,4 ; Sun, Yiqiang1,4; Men, Dandan4; Lyu, Xianjun2; Zhang, Qianling3; Cai, Weiping4; Li, Yue1,4
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| 刊名 | JOURNAL OF MATERIALS CHEMISTRY A
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| 出版日期 | 2018-10-28 |
| 卷号 | 6期号:40页码:19555-19562 |
| ISSN号 | 2050-7488 |
| DOI | 10.1039/c8ta07773h |
| 通讯作者 | Li, Yue(yueli@issp.ac.cn) |
| 英文摘要 | Currently, for overall water splitting, the highest activity for hydrogen evolution reaction (HER) oxygen evolution reaction (OER) are recorded by platinum (Pt) and ruthenium oxide (RuO2) catalysts, respectively. However, the shortage and sumptuosity of these noble metals limit their commercial applications. Herein, we prepared Ni0.33Co0.67MoS4 nanosheets on carbon fiber cloth (Ni0.33Co0.67MoS4/CFC) as bifunctional electrolytic water catalysts for both HER and OER. In the HER process, Ni0.33Co0.67MoS4/CFC exhibited an overpotential of only 48.0mV at a current density of 10 mA cm(-2), and the Tafel slope was 73.5 mV dec(-1). Moreover, in the OER process, Ni0.33Co0.67MoS4/CFC displayed a low overpotential of 283 mV at current densities of 10 mA cm(-2), and the Tafel slope was 68.8 mV dec(-1). More importantly, Ni0.33Co0.67MoS4/CFC could act as a bifunctional electrocatalyst to split water under a cell voltage of 1.55 V at a current density of 10 mA cm(-2). In addition, negligible decay occurred after 20 h of continuous electrolysis testing. Such noble-metal-free electrocatalysts may provide a strategy for the design of high efficiency overall water splitting catalysts, which are expected to be applied to the actual electrolysis water industry. |
| WOS关键词 | HYDROGEN EVOLUTION REACTION ; HIGH-PERFORMANCE ; EFFICIENT ELECTROCATALYSTS ; NANOWIRE ARRAYS ; LOW-COST ; NI FOAM ; OXYGEN ; ALKALINE ; OXIDATION ; INTERLAYER |
| 资助项目 | Natural Science Foundation of China[51771188] ; Natural Science Foundation of China[51571189] |
| WOS研究方向 | Chemistry ; Energy & Fuels ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000448413100027 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 资助机构 | Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of China ; Natural Science Foundation of China |
| 源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/39986]  |
| 专题 | 合肥物质科学研究院_中科院固体物理研究所 |
| 通讯作者 | Li, Yue |
| 作者单位 | 1.Univ Sci & Technol China, Hefei 230026, Anhui, Peoples R China 2.Shandong Univ Sci & Technol, Coll Chem & Environm Engn, Qingdao 266590, Peoples R China 3.Shenzhen Univ, Dept Chem & Chem Engn, Shenzhen 518060, Peoples R China 4.Chinese Acad Sci, Inst Solid State Phys, Anhui Key Lab Nanomat & Nanotechnol, Key Lab Mat Phys, Hefei 230031, Anhui, Peoples R China |
| 推荐引用方式 GB/T 7714 | Hang, Lifeng,Zhang, Tao,Sun, Yiqiang,et al. Ni0.33Co0.67MoS4 nanosheets as a bifunctional electrolytic water catalyst for overall water splitting[J]. JOURNAL OF MATERIALS CHEMISTRY A,2018,6(40):19555-19562. |
| APA | Hang, Lifeng.,Zhang, Tao.,Sun, Yiqiang.,Men, Dandan.,Lyu, Xianjun.,...&Li, Yue.(2018).Ni0.33Co0.67MoS4 nanosheets as a bifunctional electrolytic water catalyst for overall water splitting.JOURNAL OF MATERIALS CHEMISTRY A,6(40),19555-19562. |
| MLA | Hang, Lifeng,et al."Ni0.33Co0.67MoS4 nanosheets as a bifunctional electrolytic water catalyst for overall water splitting".JOURNAL OF MATERIALS CHEMISTRY A 6.40(2018):19555-19562. |
入库方式： OAI收割
来源：合肥物质科学研究院
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