Discovery, Mechanism, and Application of Antigalvanic Reaction
文献类型：期刊论文
| 作者 | Gan, Zibao ; Xia, Nan; Woo, Zhikun2
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| 刊名 | ACCOUNTS OF CHEMICAL RESEARCH
 |
| 出版日期 | 2018-11-01 |
| 卷号 | 51期号:11页码:2774-2783 |
| ISSN号 | 0001-4842 |
| DOI | 10.1021/acs.accounts.8b00374 |
| 通讯作者 | Woo, Zhikun(zkwu@issp.ac.cn) |
| 英文摘要 | Among many outstanding findings associated with the quantum size effect, one of the most exciting is the discovery of the antigalvanic reaction (AGR), which is the opposite of the classic galvanic reaction (GR) that has a history of nearly 240 years. The GR, named after Italian scientist Luigi Galvani, involves the spontaneous reduction of a noble-metal cation by a less noble metal in solution driven by the difference in electrochemical potentials. Classic galvanic reduction has been widely applied and has recently received particular interest in nanoscience and nanotechnology. However, the opposite of GR, that is, reduction of metal ions by less reactive (or more noble) metals, has long been regarded as a virtual impossibility until the recent surprising findings regarding atomically precise ultrasmall metal nanoparticles (nanoclusters), which bridge the gap between metal atoms (complexes) and metal nanocrystals and provide opportunities for novel scientific findings due to their well-defined compositions and structures. The AGR is significant not only because it is the opposite of the classic galvanic theory but also because it opens extensive applications in a large range of fields, such as sensing and tuning the compositions, structures, and properties of nanostructures that are otherwise difficult to obtain. Starting with the proposal of the general AGR concept in 2012 by Wu, a new era began, in which AGR received widespread attention and was extensively studied. After years of effort, great advances have been achieved in the research on AGR, which will be reviewed below. In this Account, we first provide a short introduction to the AGR concept and then discuss the driving force of the AGR together with the effecting factors, including the ligand, particle size, solvent, metal ion precursor, and ion dose. Subsequently, the application of the AGR in engineering atomically precise alloy (bimetallic and trimetallic) and monometallic nanoclusters is described, and tuning the properties of the parent nanoclusters is also included. In particular, four alloying modes (namely, (i) addition, (ii) replacement, (iii) replacement and structural transformation, and (iv) nonreplacement and structural transformation) associated with the AGR are discussed. After that, the applications of the AGR in metal ion sensing and antioxidation are reviewed. Finally, future prospects are discussed, and some challenging issues are presented at the end of this Account. It is expected that this Account will stimulate more scientific and technological interests in the AGR, and exciting progress in the understanding and application of the AGR will be made in the coming years. |
| WOS关键词 | ANTI-GALVANIC REDUCTION ; METAL EXCHANGE METHOD ; GOLD-NANOCLUSTERS ; CATALYTIC-ACTIVITY ; NANOPARTICLES ; AU-25 ; NANOSTRUCTURES ; ATOMS ; IONS |
| 资助项目 | National Natural Science Foundation of China[21222301] ; National Natural Science Foundation of China[51502299] ; National Natural Science Foundation of China[21701179] ; National Natural Science Foundation of China[21771186] ; National Natural Science Foundation of China[21829501] ; National Natural Science Foundation of China[21171170] ; National Natural Science Foundation of China[21528303] ; Natural Science Foundation of Anhui Province[1708085QB36] ; Key Program of 13th five-year plan, CASHIPS[KP-2017-16] ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology[2017FXCX002] ; CAS/SAFEA International Partnership Program for Creative Research Teams |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000451245900020 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Natural Science Foundation of Anhui Province ; Natural Science Foundation of Anhui Province ; Natural Science Foundation of Anhui Province ; Natural Science Foundation of Anhui Province ; Key Program of 13th five-year plan, CASHIPS ; Key Program of 13th five-year plan, CASHIPS ; Key Program of 13th five-year plan, CASHIPS ; Key Program of 13th five-year plan, CASHIPS ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Natural Science Foundation of Anhui Province ; Natural Science Foundation of Anhui Province ; Natural Science Foundation of Anhui Province ; Natural Science Foundation of Anhui Province ; Key Program of 13th five-year plan, CASHIPS ; Key Program of 13th five-year plan, CASHIPS ; Key Program of 13th five-year plan, CASHIPS ; Key Program of 13th five-year plan, CASHIPS ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Natural Science Foundation of Anhui Province ; Natural Science Foundation of Anhui Province ; Natural Science Foundation of Anhui Province ; Natural Science Foundation of Anhui Province ; Key Program of 13th five-year plan, CASHIPS ; Key Program of 13th five-year plan, CASHIPS ; Key Program of 13th five-year plan, CASHIPS ; Key Program of 13th five-year plan, CASHIPS ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Natural Science Foundation of Anhui Province ; Natural Science Foundation of Anhui Province ; Natural Science Foundation of Anhui Province ; Natural Science Foundation of Anhui Province ; Key Program of 13th five-year plan, CASHIPS ; Key Program of 13th five-year plan, CASHIPS ; Key Program of 13th five-year plan, CASHIPS ; Key Program of 13th five-year plan, CASHIPS ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams |
| 源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/40317]  |
| 专题 | 合肥物质科学研究院_中科院固体物理研究所 |
| 通讯作者 | Woo, Zhikun |
| 作者单位 | 1.Anhui Univ, Inst Phys Sci & Informat Technol, Hefei 230601, Anhui, Peoples R China 2.Chinese Acad Sci, Inst Solid State Phys, Key Lab Mat Phys, Anhui Key Lab Nanomat & Nanotechnol,CAS Ctr Excel, Hefei 230031, Anhui, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gan, Zibao,Xia, Nan,Woo, Zhikun. Discovery, Mechanism, and Application of Antigalvanic Reaction[J]. ACCOUNTS OF CHEMICAL RESEARCH,2018,51(11):2774-2783. |
| APA | Gan, Zibao,Xia, Nan,&Woo, Zhikun.(2018).Discovery, Mechanism, and Application of Antigalvanic Reaction.ACCOUNTS OF CHEMICAL RESEARCH,51(11),2774-2783. |
| MLA | Gan, Zibao,et al."Discovery, Mechanism, and Application of Antigalvanic Reaction".ACCOUNTS OF CHEMICAL RESEARCH 51.11(2018):2774-2783. |
入库方式： OAI收割
来源：合肥物质科学研究院
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