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The catalytic behaviour in aqueous-phase hydrogenation over a renewable Ni catalyst derived from a perovskite-type oxide

文献类型：期刊论文

作者Chen, Chun1; Fan, Ruoyu1; Gong, Wanbing1; Zhang, Haimin1; Wang, Guozhong1; Zhao, Huijun1,2
刊名DALTON TRANSACTIONS
出版日期2018-12-28
卷号47期号:48页码:17276-17284
ISSN号1477-9226
DOI10.1039/c8dt03907k
通讯作者Wang, Guozhong(gzhwang@issp.ac.cn) ; Zhao, Huijun(h.zhao@griffith.edu.au)
英文摘要Water is inevitably associated with the production of bio-derived platform molecules, but most supported metallic catalysts have poor water compatibility. Although there have been a great number of investigations regarding the hydrogenation of bio-derived unsaturated compounds in the organic phase, the reactions that proceed in water are still quite challenging. Herein, we report the synthesis of a supported nickel catalyst (Ni-LN650) by the reduction of the perovskite-type oxide LaNiO3 precursor at 650 degrees C. The derived catalyst affords attractive activity in the hydrogenation of furfural by using water as the reaction medium, in which furfural is completely converted into tetrahydrofurfuryl alcohol with the highest productivity of 289.7 mmol g(Ni)(-1) h(-1) at 120 degrees C and 1 MPa of H-2 within 5 h of reaction. The Ni-LN650 catalyst also exhibits good stability and renewability in a cycle test, stemming from the self-regeneration peculiarity of the perovskite-type oxide precursor. Moreover, the catalyst can also demonstrate high activity in the aqueous-phase hydrogenation of various aldehydes, alkenes and carboxylic acids in a series of experiments. Due to the merits of usability in water, the renewability and wide application scope, the Ni-LN650 catalyst can be treated as a promising candidate for the catalytic conversion of bio-derived platform molecules into high value-added fuels and chemicals.
WOS关键词REDUCTIVE AMINATION ; PROMISING PLATFORM ; CHEMICALS ; HYDRODEOXYGENATION ; PERFORMANCE ; CONVERSION ; METHANE ; FURAN
资助项目National Natural Science Foundation of China[51502297] ; National Natural Science Foundation of China[51871209] ; National Natural Science Foundation of China[51372248] ; National Natural Science Foundation of China[51432009] ; Instrument Developing Project of the Chinese Academy of Sciences[yz201421]
WOS研究方向Chemistry
语种英语
WOS记录号WOS:000453550900008
出版者ROYAL SOC CHEMISTRY
资助机构National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Instrument Developing Project of the Chinese Academy of Sciences ; Instrument Developing Project of the Chinese Academy of Sciences ; Instrument Developing Project of the Chinese Academy of Sciences ; Instrument Developing Project of the Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Instrument Developing Project of the Chinese Academy of Sciences ; Instrument Developing Project of the Chinese Academy of Sciences ; Instrument Developing Project of the Chinese Academy of Sciences ; Instrument Developing Project of the Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Instrument Developing Project of the Chinese Academy of Sciences ; Instrument Developing Project of the Chinese Academy of Sciences ; Instrument Developing Project of the Chinese Academy of Sciences ; Instrument Developing Project of the Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Instrument Developing Project of the Chinese Academy of Sciences ; Instrument Developing Project of the Chinese Academy of Sciences ; Instrument Developing Project of the Chinese Academy of Sciences ; Instrument Developing Project of the Chinese Academy of Sciences
源URL[http://ir.hfcas.ac.cn:8080/handle/334002/40936]  
专题合肥物质科学研究院_中科院固体物理研究所
通讯作者Wang, Guozhong; Zhao, Huijun
作者单位1.Chinese Acad Sci, Anhui Key Lab Nanomat & Nanotechnol, Key Lab Mat Phys,Inst Solid State Phys, Ctr Environm & Energy Nanomat,CAS Ctr Excellence, Hefei 230031, Anhui, Peoples R China
2.Griffith Univ, Ctr Clean Environm & Energy, Gold Coast Campus, Brisbane, Qld 4222, Australia
推荐引用方式
GB/T 7714		 Chen, Chun,Fan, Ruoyu,Gong, Wanbing,et al. The catalytic behaviour in aqueous-phase hydrogenation over a renewable Ni catalyst derived from a perovskite-type oxide[J]. DALTON TRANSACTIONS,2018,47(48):17276-17284.
APA Chen, Chun,Fan, Ruoyu,Gong, Wanbing,Zhang, Haimin,Wang, Guozhong,&Zhao, Huijun.(2018).The catalytic behaviour in aqueous-phase hydrogenation over a renewable Ni catalyst derived from a perovskite-type oxide.DALTON TRANSACTIONS,47(48),17276-17284.
MLA Chen, Chun,et al."The catalytic behaviour in aqueous-phase hydrogenation over a renewable Ni catalyst derived from a perovskite-type oxide".DALTON TRANSACTIONS 47.48(2018):17276-17284.

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来源：合肥物质科学研究院

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