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A chiral zinc(II) metal-organic framework as high selective luminescent sensor for detecting trace nitro explosives picric acid and Fe3+ ion

文献类型：期刊论文

作者Zhang, Xiaolong2; Hu, Jinsong1,2,3; Wang, Bin2; Li, Zhiqiang2; Xu, Shibing2; Chen, Yanan2; Ma, Xiangmei2
刊名JOURNAL OF SOLID STATE CHEMISTRY
出版日期2019
卷号269页码:459-464
ISSN号0022-4596
关键词Fluorescence sensing Metal-organic frameworks Picric acid Metal cations
DOI10.1016/j.jssc.2018.10.021
通讯作者Hu, Jinsong(jshu@aust.edu.cn)
英文摘要A chiral luminescent zinc(II)-MOF [Zn(BPDPE)(2)(dca)(2)](n), (1) (BPDPE=4,4'-bis(pyridy)diphenyl ether, H2dca=Dextro-camphoric acid) was obtained and structurally characterized. Complex 1 presents a 3D framework based on [Zn(BPDPE)](n) and [Zn(dca)](n) helical chains linking central metal ions, and exhibits ligand-based emission in the solution systems, which render it suitable as a bifunctional fluorescence sensing material for detecting nitro explosives and metal ions. Fluorescence titration experiments revealed that complex 1 has highly selective and sensitive fluorescence sensing performances for detecting picric acid (TNP) and Fe3+ ion through luminescence quenching. Furthermore, the luminescent intensities complex 1 were not weaken obviously after be regenerated at least four times. The sensing mechanisms of complex 1 as luminescent sensor have been studied as well.
WOS关键词ADSORPTION ; 2,4,6-TRINITROPHENOL ; TNP ; CO2 ; MOF ; 3D
资助项目National Natural Science Foundation of China[21501002] ; National Natural Science Foundation of China[21671004] ; Open Fundation of the Key Laboratory of Photochemical Conversion and Optoelectronic Material, TIPC, CAS ; Open Fundation of the Key Lab of Photovoltaic and Energy Conservation Materials ; Key Project of Natural Science Research in Anhui Colleges and Universities[KJ2016A196] ; Key Research and Development Project in Anhui Province[1804a09020090]
WOS研究方向Chemistry
语种英语
出版者ACADEMIC PRESS INC ELSEVIER SCIENCE
WOS记录号WOS:000452936800064
资助机构National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Open Fundation of the Key Laboratory of Photochemical Conversion and Optoelectronic Material, TIPC, CAS ; Open Fundation of the Key Laboratory of Photochemical Conversion and Optoelectronic Material, TIPC, CAS ; Open Fundation of the Key Laboratory of Photochemical Conversion and Optoelectronic Material, TIPC, CAS ; Open Fundation of the Key Laboratory of Photochemical Conversion and Optoelectronic Material, TIPC, CAS ; Open Fundation of the Key Lab of Photovoltaic and Energy Conservation Materials ; Open Fundation of the Key Lab of Photovoltaic and Energy Conservation Materials ; Open Fundation of the Key Lab of Photovoltaic and Energy Conservation Materials ; Open Fundation of the Key Lab of Photovoltaic and Energy Conservation Materials ; Key Project of Natural Science Research in Anhui Colleges and Universities ; Key Project of Natural Science Research in Anhui Colleges and Universities ; Key Project of Natural Science Research in Anhui Colleges and Universities ; Key Project of Natural Science Research in Anhui Colleges and Universities ; Key Research and Development Project in Anhui Province ; Key Research and Development Project in Anhui Province ; Key Research and Development Project in Anhui Province ; Key Research and Development Project in Anhui Province ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Open Fundation of the Key Laboratory of Photochemical Conversion and Optoelectronic Material, TIPC, CAS ; Open Fundation of the Key Laboratory of Photochemical Conversion and Optoelectronic Material, TIPC, CAS ; Open Fundation of the Key Laboratory of Photochemical Conversion and Optoelectronic Material, TIPC, CAS ; Open Fundation of the Key Laboratory of Photochemical Conversion and Optoelectronic Material, TIPC, CAS ; Open Fundation of the Key Lab of Photovoltaic and Energy Conservation Materials ; Open Fundation of the Key Lab of Photovoltaic and Energy Conservation Materials ; Open Fundation of the Key Lab of Photovoltaic and Energy Conservation Materials ; Open Fundation of the Key Lab of Photovoltaic and Energy Conservation Materials ; Key Project of Natural Science Research in Anhui Colleges and Universities ; Key Project of Natural Science Research in Anhui Colleges and Universities ; Key Project of Natural Science Research in Anhui Colleges and Universities ; Key Project of Natural Science Research in Anhui Colleges and Universities ; Key Research and Development Project in Anhui Province ; Key Research and Development Project in Anhui Province ; Key Research and Development Project in Anhui Province ; Key Research and Development Project in Anhui Province ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Open Fundation of the Key Laboratory of Photochemical Conversion and Optoelectronic Material, TIPC, CAS ; Open Fundation of the Key Laboratory of Photochemical Conversion and Optoelectronic Material, TIPC, CAS ; Open Fundation of the Key Laboratory of Photochemical Conversion and Optoelectronic Material, TIPC, CAS ; Open Fundation of the Key Laboratory of Photochemical Conversion and Optoelectronic Material, TIPC, CAS ; Open Fundation of the Key Lab of Photovoltaic and Energy Conservation Materials ; Open Fundation of the Key Lab of Photovoltaic and Energy Conservation Materials ; Open Fundation of the Key Lab of Photovoltaic and Energy Conservation Materials ; Open Fundation of the Key Lab of Photovoltaic and Energy Conservation Materials ; Key Project of Natural Science Research in Anhui Colleges and Universities ; Key Project of Natural Science Research in Anhui Colleges and Universities ; Key Project of Natural Science Research in Anhui Colleges and Universities ; Key Project of Natural Science Research in Anhui Colleges and Universities ; Key Research and Development Project in Anhui Province ; Key Research and Development Project in Anhui Province ; Key Research and Development Project in Anhui Province ; Key Research and Development Project in Anhui Province ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Open Fundation of the Key Laboratory of Photochemical Conversion and Optoelectronic Material, TIPC, CAS ; Open Fundation of the Key Laboratory of Photochemical Conversion and Optoelectronic Material, TIPC, CAS ; Open Fundation of the Key Laboratory of Photochemical Conversion and Optoelectronic Material, TIPC, CAS ; Open Fundation of the Key Laboratory of Photochemical Conversion and Optoelectronic Material, TIPC, CAS ; Open Fundation of the Key Lab of Photovoltaic and Energy Conservation Materials ; Open Fundation of the Key Lab of Photovoltaic and Energy Conservation Materials ; Open Fundation of the Key Lab of Photovoltaic and Energy Conservation Materials ; Open Fundation of the Key Lab of Photovoltaic and Energy Conservation Materials ; Key Project of Natural Science Research in Anhui Colleges and Universities ; Key Project of Natural Science Research in Anhui Colleges and Universities ; Key Project of Natural Science Research in Anhui Colleges and Universities ; Key Project of Natural Science Research in Anhui Colleges and Universities ; Key Research and Development Project in Anhui Province ; Key Research and Development Project in Anhui Province ; Key Research and Development Project in Anhui Province ; Key Research and Development Project in Anhui Province
源URL[http://ir.hfcas.ac.cn:8080/handle/334002/40939]  
专题中国科学院合肥物质科学研究院
通讯作者Hu, Jinsong
作者单位1.Chinese Acad Sci, Hefei Inst Phys Sci, Key Lab Photovolta & Energy Conservat Mat, Beijing, Peoples R China
2.Anhui Univ Sci & Technol, Sch Chem Engn, Huainan 232001, Peoples R China
3.Chinese Acad Sci, TIPC, Key Lab Photochem Convers & Optoelect Mat, Beijing, Peoples R China
推荐引用方式
GB/T 7714		 Zhang, Xiaolong,Hu, Jinsong,Wang, Bin,et al. A chiral zinc(II) metal-organic framework as high selective luminescent sensor for detecting trace nitro explosives picric acid and Fe3+ ion[J]. JOURNAL OF SOLID STATE CHEMISTRY,2019,269:459-464.
APA Zhang, Xiaolong.,Hu, Jinsong.,Wang, Bin.,Li, Zhiqiang.,Xu, Shibing.,...&Ma, Xiangmei.(2019).A chiral zinc(II) metal-organic framework as high selective luminescent sensor for detecting trace nitro explosives picric acid and Fe3+ ion.JOURNAL OF SOLID STATE CHEMISTRY,269,459-464.
MLA Zhang, Xiaolong,et al."A chiral zinc(II) metal-organic framework as high selective luminescent sensor for detecting trace nitro explosives picric acid and Fe3+ ion".JOURNAL OF SOLID STATE CHEMISTRY 269(2019):459-464.

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来源：合肥物质科学研究院

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