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Carbon Nanotubes with Cobalt Corroles for Hydrogen and Oxygen Evolution in pH 0-14 Solutions

文献类型：期刊论文

作者Li, Xialiang5; Lei, Haitao5; Liu, Jieyu2,3; Zhao, Xueli5; Ding, Shuping5; Zhang, Zongyao1; Tao, Xixi4; Zhang, Wei5; Wang, Weichao2,3; Zheng, Xiaohong4
刊名ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
出版日期2018-11-12
卷号57期号:46页码:15070-15075
关键词carbon nanotubes cobalt corroles hydrogen evolution oxygen evolution water splitting
ISSN号1433-7851
DOI10.1002/anie.201807996
通讯作者Zheng, Xiaohong(xhzheng@theory.issp.ac.cn) ; Cao, Rui(ruicao@ruc.edu.cn)
英文摘要Water splitting is promising to realize a hydrogen-based society. The practical use of molecular water-splitting catalysts relies on their integration onto electrode materials. We describe herein the immobilization of cobalt corroles on carbon nanotubes (CNTs) by four strategies and compare the performance of the resulting hybrids for H-2 and O-2 evolution. Co corroles can be covalently attached to CNTs with short conjugated linkers (the hybrid is denoted as H1) or with long alkane chains (H2), or can be grafted to CNTs via strong pi-pi interactions (H3) or via simple adsorption (H4). An activity trend H1 >> H3> H2 approximate to H4 is obtained for H-2 and O-2 evolution, showing the critical role of electron transfer ability on electrocatalysis. Notably, H1 is the first Janus catalyst for both H-2 and O-2 evolution reactions in pH 0-14 aqueous solutions. Therefore, this work is significant to show potential uses of electrode materials with well-designed molecular catalysts in electrocatalysis.
WOS关键词WATER-OXIDATION ; NONCOVALENT IMMOBILIZATION ; CO2-TO-CO CONVERSION ; MOLECULAR CATALYSTS ; O-2 REDUCTION ; ELECTROCATALYST ; PORPHYRIN ; COMPLEX ; COMPOSITE ; LIGAND
资助项目Thousand Talents Program of China ; Fok Ying-Tong Education Foundation for Outstanding Young Teachers in University ; National Natural Science Foundation of China[21101170] ; National Natural Science Foundation of China[21573139] ; National Natural Science Foundation of China[21773146] ; Fundamental Research Funds for the Central Universities ; Shaanxi Normal University
WOS研究方向Chemistry
语种英语
WOS记录号WOS:000452396800013
出版者WILEY-V C H VERLAG GMBH
资助机构Thousand Talents Program of China ; Thousand Talents Program of China ; Thousand Talents Program of China ; Thousand Talents Program of China ; Fok Ying-Tong Education Foundation for Outstanding Young Teachers in University ; Fok Ying-Tong Education Foundation for Outstanding Young Teachers in University ; Fok Ying-Tong Education Foundation for Outstanding Young Teachers in University ; Fok Ying-Tong Education Foundation for Outstanding Young Teachers in University ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Shaanxi Normal University ; Shaanxi Normal University ; Shaanxi Normal University ; Shaanxi Normal University ; Thousand Talents Program of China ; Thousand Talents Program of China ; Thousand Talents Program of China ; Thousand Talents Program of China ; Fok Ying-Tong Education Foundation for Outstanding Young Teachers in University ; Fok Ying-Tong Education Foundation for Outstanding Young Teachers in University ; Fok Ying-Tong Education Foundation for Outstanding Young Teachers in University ; Fok Ying-Tong Education Foundation for Outstanding Young Teachers in University ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Shaanxi Normal University ; Shaanxi Normal University ; Shaanxi Normal University ; Shaanxi Normal University ; Thousand Talents Program of China ; Thousand Talents Program of China ; Thousand Talents Program of China ; Thousand Talents Program of China ; Fok Ying-Tong Education Foundation for Outstanding Young Teachers in University ; Fok Ying-Tong Education Foundation for Outstanding Young Teachers in University ; Fok Ying-Tong Education Foundation for Outstanding Young Teachers in University ; Fok Ying-Tong Education Foundation for Outstanding Young Teachers in University ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Shaanxi Normal University ; Shaanxi Normal University ; Shaanxi Normal University ; Shaanxi Normal University ; Thousand Talents Program of China ; Thousand Talents Program of China ; Thousand Talents Program of China ; Thousand Talents Program of China ; Fok Ying-Tong Education Foundation for Outstanding Young Teachers in University ; Fok Ying-Tong Education Foundation for Outstanding Young Teachers in University ; Fok Ying-Tong Education Foundation for Outstanding Young Teachers in University ; Fok Ying-Tong Education Foundation for Outstanding Young Teachers in University ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Shaanxi Normal University ; Shaanxi Normal University ; Shaanxi Normal University ; Shaanxi Normal University
源URL[http://ir.hfcas.ac.cn:8080/handle/334002/41060]  
专题合肥物质科学研究院_中科院固体物理研究所
通讯作者Zheng, Xiaohong; Cao, Rui
作者单位1.Renmin Univ China, Dept Chem, Beijing 100872, Peoples R China
2.Nankai Univ, Dept Elect, Tianjin 300071, Peoples R China
3.Nankai Univ, Key Lab Photoelect Thin Film Devices & Technol Ti, Tianjin 300071, Peoples R China
4.Chinese Acad Sci, Inst Solid State Phys, Key Lab Mat Phys, Hefei 230031, Anhui, Peoples R China
5.Shaanxi Normal Univ, Sch Chem & Chem Engn, Minist Educ, Key Lab Appl Surface & Colloid Chem, Xian 710119, Shaanxi, Peoples R China
推荐引用方式
GB/T 7714		 Li, Xialiang,Lei, Haitao,Liu, Jieyu,et al. Carbon Nanotubes with Cobalt Corroles for Hydrogen and Oxygen Evolution in pH 0-14 Solutions[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2018,57(46):15070-15075.
APA Li, Xialiang.,Lei, Haitao.,Liu, Jieyu.,Zhao, Xueli.,Ding, Shuping.,...&Cao, Rui.(2018).Carbon Nanotubes with Cobalt Corroles for Hydrogen and Oxygen Evolution in pH 0-14 Solutions.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,57(46),15070-15075.
MLA Li, Xialiang,et al."Carbon Nanotubes with Cobalt Corroles for Hydrogen and Oxygen Evolution in pH 0-14 Solutions".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 57.46(2018):15070-15075.

入库方式： OAI收割

来源：合肥物质科学研究院

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