Free Radical Pathway Cleavage of C-O Bonds for the Synthesis of Alkylboron Compounds
文献类型：期刊论文
| 作者 | Lu, Xi1; Zhang, Zhen-Qi1; Yu, Lu2; Zhang, Ben1; Wang, Bing1; Gong, Tian-Jun1; Tian, Chang-Lin1,2,3; Xiao, Bin1; Fu, Yao1 |
| 刊名 | CHINESE JOURNAL OF CHEMISTRY
 |
| 出版日期 | 2019 |
| 卷号 | 37期号:1页码:11-18 |
| 关键词 | radical reactions alcohols borates silver cross-coupling |
| ISSN号 | 1001-604X |
| DOI | 10.1002/cjoc.201800500 |
| 通讯作者 | Fu, Yao(fuyao@ustc.edu.cn) |
| 英文摘要 | .Summary of main observation and conclusion We report a silver-catalyzed borylation of alkyl tosylates, which provides a new method for the synthesis of alkylboron compounds with good functional group compatibility and excellent chemoselectivity. The present work added highly polarized alkyl tosylate C-O bonds to the fairly limited number of C-O bonds able to participate in free radical cleavage pathways. The mechanistic studies suggested that in situ-generated silver(0) catalytic species were the active catalytic species and played a key role in the radical pathway cleavage of C-O bonds. |
| WOS关键词 | LITHIATION-BORYLATION METHODOLOGY ; NICKEL-CATALYZED BORYLATION ; CROSS-COUPLING REACTIONS ; STEREOSPECIFIC SYNTHESIS ; SECONDARY ; TOSYLATES ; TERTIARY ; HALIDES ; ARYL ; BORON |
| 资助项目 | National Natural Science Foundation of China[21472181] ; National Natural Science Foundation of China[21572212] ; National Natural Science Foundation of China[21502184] ; National Natural Science Foundation of China[21732006] ; National Natural Science Foundation of China[21702200] ; National Natural Science Foundation of China[51821006] ; Major Program of Development Foundation of Hefei Center for Physical Science and Technology[2017FXZY001] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000453403000002 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 资助机构 | National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Major Program of Development Foundation of Hefei Center for Physical Science and Technology ; Major Program of Development Foundation of Hefei Center for Physical Science and Technology ; Major Program of Development Foundation of Hefei Center for Physical Science and Technology ; Major Program of Development Foundation of Hefei Center for Physical Science and Technology ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Major Program of Development Foundation of Hefei Center for Physical Science and Technology ; Major Program of Development Foundation of Hefei Center for Physical Science and Technology ; Major Program of Development Foundation of Hefei Center for Physical Science and Technology ; Major Program of Development Foundation of Hefei Center for Physical Science and Technology ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Major Program of Development Foundation of Hefei Center for Physical Science and Technology ; Major Program of Development Foundation of Hefei Center for Physical Science and Technology ; Major Program of Development Foundation of Hefei Center for Physical Science and Technology ; Major Program of Development Foundation of Hefei Center for Physical Science and Technology ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Major Program of Development Foundation of Hefei Center for Physical Science and Technology ; Major Program of Development Foundation of Hefei Center for Physical Science and Technology ; Major Program of Development Foundation of Hefei Center for Physical Science and Technology ; Major Program of Development Foundation of Hefei Center for Physical Science and Technology |
| 源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/40987]  |
| 专题 | 合肥物质科学研究院_中科院强磁场科学中心 |
| 通讯作者 | Fu, Yao |
| 作者单位 | 1.Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, CAS Key Lab Urban Pollutant Convers, Anhui Prov Key Lab Biomass Clean Energy,iChEM, Hefei 230026, Anhui, Peoples R China 2.Chinese Acad Sci, High Field Magnet Lab, Hefei 230031, Anhui, Peoples R China 3.Univ Sci & Technol China, Sch Life Sci, Hefei 230027, Anhui, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lu, Xi,Zhang, Zhen-Qi,Yu, Lu,et al. Free Radical Pathway Cleavage of C-O Bonds for the Synthesis of Alkylboron Compounds[J]. CHINESE JOURNAL OF CHEMISTRY,2019,37(1):11-18. |
| APA | Lu, Xi.,Zhang, Zhen-Qi.,Yu, Lu.,Zhang, Ben.,Wang, Bing.,...&Fu, Yao.(2019).Free Radical Pathway Cleavage of C-O Bonds for the Synthesis of Alkylboron Compounds.CHINESE JOURNAL OF CHEMISTRY,37(1),11-18. |
| MLA | Lu, Xi,et al."Free Radical Pathway Cleavage of C-O Bonds for the Synthesis of Alkylboron Compounds".CHINESE JOURNAL OF CHEMISTRY 37.1(2019):11-18. |
入库方式： OAI收割
来源：合肥物质科学研究院
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