Synthesis and Characterization of Novel Trifluoromethylphenyl Silane Monomers
文献类型：期刊论文
| 作者 | Li ZX(李战雄) ; DU LIPING ; Tang SQ(唐松青) ; Wang CY(王昌尧) |
| 刊名 | Chin. J. Chem.
 |
| 出版日期 | 2009 |
| 卷号 | 27期号:12页码:2429-2432 |
| ISSN号 | 1001-604X |
| 其他题名 | Synthesis and Characterization of Novel Trifluoromethylphenyl Silane Monomers |
| 通讯作者 | 唐松青 |
| 英文摘要 | Using 3,5 -bis(trifluoromethyl)bromobenzene and methyltrimethoxysilane or tetraethoxysilane as raw materials, novel trifluoromethylphenyl silanes were synthesized via Grignard reaction and substitution reaction, and the molecular structure of silane products was characterized by NMR, FT-IR, MS techniques and elemental analysis. The reaction result showed that the reactivity of Grignard reagent was different in THF and diethyl ether when subjected to substitution reaction, which gave three products with different substitution degree. According to the current work, mono-, di- and tri-substituted product can be obtained selectively from the same reactants by controlling the reaction condition. |
| 学科主题 | 氟化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1002/cjoc.201090021 |
| 语种 | 英语 |
| WOS记录号 | WOS:000273627600022 |
| 公开日期 | 2013-08-21 |
| 源URL | [http://202.127.28.38/handle/331003/27765]  |
| 专题 | 上海有机化学研究所_上海有机化学研究所 |
| 推荐引用方式 GB/T 7714 | Li ZX,DU LIPING,Tang SQ,et al. Synthesis and Characterization of Novel Trifluoromethylphenyl Silane Monomers[J]. Chin. J. Chem.,2009,27(12):2429-2432. |
| APA | 李战雄,DU LIPING,唐松青,&王昌尧.(2009).Synthesis and Characterization of Novel Trifluoromethylphenyl Silane Monomers.Chin. J. Chem.,27(12),2429-2432. |
| MLA | 李战雄,et al."Synthesis and Characterization of Novel Trifluoromethylphenyl Silane Monomers".Chin. J. Chem. 27.12(2009):2429-2432. |
入库方式： OAI收割
来源：上海有机化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。