中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Polymeric Ladderphanes

文献类型:期刊论文

作者Zhou ZM(周志明) ; Li SL(李升隆) ; Chen ZX(陈至贤) ; Biju, Akkattu Thankappan ; Wang XW(王献文) ; Wu YL(吴宜霖) ; Zhang GF(张国富) ; Yang GW(杨光伟) ; Lin ZX(林宗欣) ; Huang MJ(黄明杰) ; Cai BY(蔡伯宇) ; Lin JQ(林金泉) ; Huang SL(黄守龄) ; Chen JX(陈俊显) ; Lu TY(陆天尧)
刊名J. Am. Chem. Soc.
出版日期2009
卷号131期号:35页码:12579-12585
ISSN号0002-7863
其他题名聚合的梯蕃
通讯作者陈俊显 ; 陆天尧
英文摘要A new class of polymers, which have a double-stranded polybinorbornene skeleton with multilayer planar oligoaryl linkers, defined as polymeric ladderphanes, are synthesized. The structures of these ladderphanes are determined by spectroscopic means. Photophysical studies and time-resolved fluorescence spectroscopic investigations reveal that there is a strong interaction between the chromophore linkers. Thus, Sorel band splitting in the absorption spectrum of the polymer with porphyrin linker (12e), significant fluorescence quenching with oligoaryl linkers (12b-d), and excimer emission with a terphenylene-diethynylene linker (12a) are characteristic photophysical properties of these polymers. Scanning tunneling microscopy shows that polymers 12b and d exhibit a ladder-like morphology and form a supramolecular assembly leading to a two-dimensional ordered array on a highly oriented pyrolytic graphite surface.
学科主题高分子化学
收录类别SCI
原文出处http://dx.doi.org/10.1021/ja9035362
语种英语
WOS记录号WOS:000269735800031
公开日期2013-08-21
源URL[http://202.127.28.38/handle/331003/27771]  
专题上海有机化学研究所_上海有机化学研究所
推荐引用方式
GB/T 7714
Zhou ZM,Li SL,Chen ZX,et al. Polymeric Ladderphanes[J]. J. Am. Chem. Soc.,2009,131(35):12579-12585.
APA 周志明.,李升隆.,陈至贤.,Biju, Akkattu Thankappan.,王献文.,...&陆天尧.(2009).Polymeric Ladderphanes.J. Am. Chem. Soc.,131(35),12579-12585.
MLA 周志明,et al."Polymeric Ladderphanes".J. Am. Chem. Soc. 131.35(2009):12579-12585.

入库方式: OAI收割

来源:上海有机化学研究所

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