Polymeric Ladderphanes
文献类型:期刊论文
作者 | Zhou ZM(周志明) ; Li SL(李升隆) ; Chen ZX(陈至贤) ; Biju, Akkattu Thankappan ; Wang XW(王献文) ; Wu YL(吴宜霖) ; Zhang GF(张国富) ; Yang GW(杨光伟) ; Lin ZX(林宗欣) ; Huang MJ(黄明杰) ; Cai BY(蔡伯宇) ; Lin JQ(林金泉) ; Huang SL(黄守龄) ; Chen JX(陈俊显) ; Lu TY(陆天尧) |
刊名 | J. Am. Chem. Soc.
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出版日期 | 2009 |
卷号 | 131期号:35页码:12579-12585 |
ISSN号 | 0002-7863 |
其他题名 | 聚合的梯蕃 |
通讯作者 | 陈俊显 ; 陆天尧 |
英文摘要 | A new class of polymers, which have a double-stranded polybinorbornene skeleton with multilayer planar oligoaryl linkers, defined as polymeric ladderphanes, are synthesized. The structures of these ladderphanes are determined by spectroscopic means. Photophysical studies and time-resolved fluorescence spectroscopic investigations reveal that there is a strong interaction between the chromophore linkers. Thus, Sorel band splitting in the absorption spectrum of the polymer with porphyrin linker (12e), significant fluorescence quenching with oligoaryl linkers (12b-d), and excimer emission with a terphenylene-diethynylene linker (12a) are characteristic photophysical properties of these polymers. Scanning tunneling microscopy shows that polymers 12b and d exhibit a ladder-like morphology and form a supramolecular assembly leading to a two-dimensional ordered array on a highly oriented pyrolytic graphite surface. |
学科主题 | 高分子化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1021/ja9035362 |
语种 | 英语 |
WOS记录号 | WOS:000269735800031 |
公开日期 | 2013-08-21 |
源URL | [http://202.127.28.38/handle/331003/27771] ![]() |
专题 | 上海有机化学研究所_上海有机化学研究所 |
推荐引用方式 GB/T 7714 | Zhou ZM,Li SL,Chen ZX,et al. Polymeric Ladderphanes[J]. J. Am. Chem. Soc.,2009,131(35):12579-12585. |
APA | 周志明.,李升隆.,陈至贤.,Biju, Akkattu Thankappan.,王献文.,...&陆天尧.(2009).Polymeric Ladderphanes.J. Am. Chem. Soc.,131(35),12579-12585. |
MLA | 周志明,et al."Polymeric Ladderphanes".J. Am. Chem. Soc. 131.35(2009):12579-12585. |
入库方式: OAI收割
来源:上海有机化学研究所
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