Ru-catalyzed Asymmetric Hydrogenation of Aryl Ketones Using Tetrazole Derived NH2-hybrid Ligand
文献类型：期刊论文
| 作者 | Bie FS(别福升) ; Li YH(李跃辉) ; Cao WG(曹卫国) ; Christian A. Sandoval |
| 刊名 | Chin. J. Chem.
 |
| 出版日期 | 2009 |
| 卷号 | 27期号:12页码:2309-2315 |
| ISSN号 | 1001-604X |
| 其他题名 | Ru-catalyzed Asymmetric Hydrogenation of Aryl Ketones Using Tetrazole Derived NH2-hybrid Ligand |
| 通讯作者 | Christian A. Sandoval |
| 英文摘要 | Readily available chiral hybrid NH2/tetrazole ligand [(S)-TEA, 1] in combination with Ru-BINAP or Ru-DIOP complexes catalyzes the asymmetric hydrogenation of a number of simple ketones with moderate enantioselectivity (up to 72% ee). The tetrazole functionality results in reversal of the typically observed chiral-induction for related systems and allows for hydrogenation to be uncharacteristically conducted in (non-protic) THF solvent. The observed catalyst performance is sensitive to the reaction conditions employed and the particular compounds involved. The origins of such features are considered to derive from the added functionality provided by the tetrazole moiety in 1, which due to its modular nature provides a good basis for further development. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1002/cjoc.201090000 |
| 语种 | 英语 |
| WOS记录号 | WOS:000273627600001 |
| 公开日期 | 2013-08-21 |
| 源URL | [http://202.127.28.38/handle/331003/27791]  |
| 专题 | 上海有机化学研究所_上海有机化学研究所 |
| 推荐引用方式 GB/T 7714 | Bie FS,Li YH,Cao WG,et al. Ru-catalyzed Asymmetric Hydrogenation of Aryl Ketones Using Tetrazole Derived NH2-hybrid Ligand[J]. Chin. J. Chem.,2009,27(12):2309-2315. |
| APA | 别福升,李跃辉,曹卫国,&Christian A. Sandoval.(2009).Ru-catalyzed Asymmetric Hydrogenation of Aryl Ketones Using Tetrazole Derived NH2-hybrid Ligand.Chin. J. Chem.,27(12),2309-2315. |
| MLA | 别福升,et al."Ru-catalyzed Asymmetric Hydrogenation of Aryl Ketones Using Tetrazole Derived NH2-hybrid Ligand".Chin. J. Chem. 27.12(2009):2309-2315. |
入库方式： OAI收割
来源：上海有机化学研究所
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