A new approach to the bicyclo[3.3.1]nonane framework of huperzine A-like molecules via palladium-catalyzed intramolecular gamma-arylation
文献类型：期刊论文
| 作者 | Ding R(丁瑞) ; Lu YY(卢云宇) ; Yao HQ(姚和权) ; Sun BF(孙炳峰) ; Lin GQ(林国强) |
| 刊名 | Sci. China-Chem.
 |
| 出版日期 | 2012 |
| 卷号 | 55期号:6页码:1097-1100 |
| ISSN号 | 1674-7291 |
| 其他题名 | 运用钯催化的分子内r-芳基化反应来构建石杉碱类双环[3.3.1]壬烷结构的新方法 |
| 通讯作者 | 孙炳峰 ; 林国强 |
| 英文摘要 | In our synthetic studies toward huperzine A, a diastereoselective alpha'-alkylation of the alpha-amido-gamma-methyl hexenone 4 was realized through a dianion intermediate which significantly enhanced the reactivity. Under the attempted Heck reaction conditions, an unexpected and unprecedented palladium-catalyzed intramolecular gamma-arylation of 3 was observed, which generated 18 with bicyclo[3.3.1]nonane framework in satisfactory yield. |
| 学科主题 | 天然产物有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1007/s11426-011-4480-y |
| 语种 | 英语 |
| WOS记录号 | WOS:000305238400031 |
| 公开日期 | 2013-08-29 |
| 源URL | [http://202.127.28.38/handle/331003/28597]  |
| 专题 | 上海有机化学研究所_中科院天然产物有机化学重点实验室 |
| 推荐引用方式 GB/T 7714 | Ding R,Lu YY,Yao HQ,et al. A new approach to the bicyclo[3.3.1]nonane framework of huperzine A-like molecules via palladium-catalyzed intramolecular gamma-arylation[J]. Sci. China-Chem.,2012,55(6):1097-1100. |
| APA | 丁瑞,卢云宇,姚和权,孙炳峰,&林国强.(2012).A new approach to the bicyclo[3.3.1]nonane framework of huperzine A-like molecules via palladium-catalyzed intramolecular gamma-arylation.Sci. China-Chem.,55(6),1097-1100. |
| MLA | 丁瑞,et al."A new approach to the bicyclo[3.3.1]nonane framework of huperzine A-like molecules via palladium-catalyzed intramolecular gamma-arylation".Sci. China-Chem. 55.6(2012):1097-1100. |
入库方式： OAI收割
来源：上海有机化学研究所
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