Efficient organocatalysts derived from simple chiral acyclic amino acids in asymmetric catalysis
文献类型:期刊论文
作者 | Chai Z(柴卓) ; Zhao G(赵刚) |
刊名 | Catal. Sci. Technol.
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出版日期 | 2012 |
卷号 | 2期号:1页码:29-41 |
ISSN号 | 2044-4753 |
其他题名 | 基于氨基酸的有机催化剂设计、合成及其在不对称催化中的应用 |
通讯作者 | 赵刚 |
英文摘要 | Chiral amino acids have played a key role in the development of organocatalysis from a biomimetic concept to an independent methodology, together with metal catalysis and enzyme catalysis, comprising the three major catalytic methodologies in modern organic synthesis. As an excellent pool for the design of organocatalysts, chiral amino acids have two obvious advantages: ready availability with usually affordable costs and modular structures allowing facile tuning of the catalytic efficiency. Recently, bifunctional/multifunctional primary-secondary amines, tertiary amine-thioureas, aminophosphines easily prepared from simple acyclic amino acids have been developed as efficient organocatalysts for various asymmetric reactions leading to a variety of useful chiral compounds. In this perspective, we present a personal overview of some of these recent advances in this field based on our own research experience. |
学科主题 | 天然产物有机化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1039/c1cy00347j |
语种 | 英语 |
WOS记录号 | WOS:000299011200003 |
公开日期 | 2013-08-29 |
源URL | [http://202.127.28.38/handle/331003/28625] ![]() |
专题 | 上海有机化学研究所_中科院天然产物有机化学重点实验室 |
推荐引用方式 GB/T 7714 | Chai Z,Zhao G. Efficient organocatalysts derived from simple chiral acyclic amino acids in asymmetric catalysis[J]. Catal. Sci. Technol.,2012,2(1):29-41. |
APA | 柴卓,&赵刚.(2012).Efficient organocatalysts derived from simple chiral acyclic amino acids in asymmetric catalysis.Catal. Sci. Technol.,2(1),29-41. |
MLA | 柴卓,et al."Efficient organocatalysts derived from simple chiral acyclic amino acids in asymmetric catalysis".Catal. Sci. Technol. 2.1(2012):29-41. |
入库方式: OAI收割
来源:上海有机化学研究所
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