Palladium-Catalyzed Aerobic Dehydrogenative Cross-Coupling of Polyfluoroarenes with Thiophenes: Facile Access to Polyfluoroarene-Thiophene Structure
文献类型：期刊论文
| 作者 | He CY(贺春阳) ; Min QQ(闵巧桥) ; Zhang XG(张新刚) |
| 刊名 | Organometallics
 |
| 出版日期 | 2012 |
| 卷号 | 31期号:4页码:1335-1340 |
| ISSN号 | 0276-7333 |
| 其他题名 | 氧气氛围下Pd-催化的多氟芳烃与噻吩的脱氢交叉偶联反应 |
| 通讯作者 | 张新刚 |
| 英文摘要 | We report a Pd-catalyzed aerobic dehydrogenative cross-coupling of polyfluoroarenes with thiophenes via 2-fold C-H functionalization. The advantages of this reaction are its high reaction efficiency, excellent functional group compatibility, and use of molecular O-2 as terminal oxidant. This reaction provides a useful and facile protocol for the preparation of polyfluoroarene thiophene structure of interest in functional materials. Mechanistic studies revealed that the reaction is initiated by the C-H bond cleavage of polyfluoroarenes. |
| 学科主题 | 氟化学 ; 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1021/om200873j |
| 语种 | 英语 |
| WOS记录号 | WOS:000300738800014 |
| 公开日期 | 2013-08-23 |
| 源URL | [http://202.127.28.38/handle/331003/28273]  |
| 专题 | 上海有机化学研究所_中科院有机氟化学重点实验室 |
| 推荐引用方式 GB/T 7714 | He CY,Min QQ,Zhang XG. Palladium-Catalyzed Aerobic Dehydrogenative Cross-Coupling of Polyfluoroarenes with Thiophenes: Facile Access to Polyfluoroarene-Thiophene Structure[J]. Organometallics,2012,31(4):1335-1340. |
| APA | 贺春阳,闵巧桥,&张新刚.(2012).Palladium-Catalyzed Aerobic Dehydrogenative Cross-Coupling of Polyfluoroarenes with Thiophenes: Facile Access to Polyfluoroarene-Thiophene Structure.Organometallics,31(4),1335-1340. |
| MLA | 贺春阳,et al."Palladium-Catalyzed Aerobic Dehydrogenative Cross-Coupling of Polyfluoroarenes with Thiophenes: Facile Access to Polyfluoroarene-Thiophene Structure".Organometallics 31.4(2012):1335-1340. |
入库方式： OAI收割
来源：上海有机化学研究所
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