Preparation of Trifluorostyrenes via Palladium-Catalyzed Coupling of Arylboronic Acids with Chloro- and Bromotrifluoroethylene
文献类型:期刊论文
作者 | XU CHUNFA ; CHEN SHENG ; Lv L(吕龙) ; Shen QL(沈其龙) |
刊名 | J. Org. Chem.
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出版日期 | 2012 |
卷号 | 77期号:22页码:10314-10320 |
ISSN号 | 0022-3263 |
其他题名 | 通过三氟氯乙烯和三氟溴乙烯与硼酸的钯催化偶联反应制备三氟苯乙烯 |
通讯作者 | 吕龙 ; 沈其龙 |
英文摘要 | A highly efficient and cost-effective method for the preparation of alpha,beta,beta-trifluorostyrene (TFS) and its derivatives is described. The method required only 0.2 mol % of Pd(dba)(2) and 0.4 mol % of (PBu3)-Bu-t and occurred to full conversion within 2.0 h. With this method, a wide range of arylboronic acids were efficiently incorporated to generate alpha,beta,beta-trifluorostyrene derivatives. |
学科主题 | 氟化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1021/jo301998g |
语种 | 英语 |
WOS记录号 | WOS:000311073000037 |
公开日期 | 2013-08-23 |
源URL | [http://202.127.28.38/handle/331003/28351] ![]() |
专题 | 上海有机化学研究所_中科院有机氟化学重点实验室 |
推荐引用方式 GB/T 7714 | XU CHUNFA,CHEN SHENG,Lv L,et al. Preparation of Trifluorostyrenes via Palladium-Catalyzed Coupling of Arylboronic Acids with Chloro- and Bromotrifluoroethylene[J]. J. Org. Chem.,2012,77(22):10314-10320. |
APA | XU CHUNFA,CHEN SHENG,吕龙,&沈其龙.(2012).Preparation of Trifluorostyrenes via Palladium-Catalyzed Coupling of Arylboronic Acids with Chloro- and Bromotrifluoroethylene.J. Org. Chem.,77(22),10314-10320. |
MLA | XU CHUNFA,et al."Preparation of Trifluorostyrenes via Palladium-Catalyzed Coupling of Arylboronic Acids with Chloro- and Bromotrifluoroethylene".J. Org. Chem. 77.22(2012):10314-10320. |
入库方式: OAI收割
来源:上海有机化学研究所
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