Side-Arm-Promoted Highly Enantioselective Ring-Opening Reactions and Kinetic Resolution of Donor-Acceptor Cyclopropanes with Amines
文献类型：期刊论文
| 作者 | Zhou YY(周友运) ; Wang LJ(王丽佳) ; Li J(李军) ; Sun XL(孙秀丽) ; Tang Y(唐勇) |
| 刊名 | J. Am. Chem. Soc.
 |
| 出版日期 | 2012 |
| 卷号 | 134期号:22页码:9066-9069 |
| ISSN号 | 0002-7863 |
| 其他题名 | 边臂促进的胺对D-A环丙烷的高对映选择性开环反应及其动力学拆分的研究 |
| 通讯作者 | 孙秀丽 ; 唐勇 |
| 英文摘要 | A Ni-catalyzed asymmetric ring-opening reaction of 2-substituted cyclopropane-1,1-dicarboxylates with aliphatic amines has been accomplished using the chiral indane-trisoxazoline (In-TOX) ligand. This highly enantioselective reaction provides an efficient approach to a variety of chiral gamma-substituted gamma-amino acid derivatives, which are readily transformed into multifunctionalized piperidines and gamma-lactams. The single-crystal X-ray structure of the TOX-Ni complex is provided, and the role of the side arm in the chiral ligand is discussed. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1021/ja302691r |
| 语种 | 英语 |
| WOS记录号 | WOS:000304837800012 |
| 公开日期 | 2013-08-22 |
| 源URL | [http://202.127.28.38/handle/331003/27973]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Zhou YY,Wang LJ,Li J,et al. Side-Arm-Promoted Highly Enantioselective Ring-Opening Reactions and Kinetic Resolution of Donor-Acceptor Cyclopropanes with Amines[J]. J. Am. Chem. Soc.,2012,134(22):9066-9069. |
| APA | 周友运,王丽佳,李军,孙秀丽,&唐勇.(2012).Side-Arm-Promoted Highly Enantioselective Ring-Opening Reactions and Kinetic Resolution of Donor-Acceptor Cyclopropanes with Amines.J. Am. Chem. Soc.,134(22),9066-9069. |
| MLA | 周友运,et al."Side-Arm-Promoted Highly Enantioselective Ring-Opening Reactions and Kinetic Resolution of Donor-Acceptor Cyclopropanes with Amines".J. Am. Chem. Soc. 134.22(2012):9066-9069. |
入库方式： OAI收割
来源：上海有机化学研究所
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