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Palladium-Catalyzed Oxidative Aryltrifluoromethylation of Activated Alkenes at Room Temperature
文献类型：期刊论文
| 作者 | Mu X(慕欣) ; Wu T(吴涛) ; Wang HY(王昊阳) ; Guo YL(郭寅龙) ; Liu GS(刘国胜) |
| 刊名 | J. Am. Chem. Soc.
 |
| 出版日期 | 2012 |
| 卷号 | 134期号:2页码:878-881 |
| ISSN号 | 0002-7863 |
| 其他题名 | 室温下钯催化活性烯烃的氧化芳基烷基化反应 |
| 通讯作者 | 刘国胜 |
| 英文摘要 | A palladium-catalyzed intramolecular oxidative aryltrifluoromethylation reaction of activated alkenes has been explored. The reaction allows for an efficient synthesis of a variety of CF3-containing oxindoles. Preliminary mechanistic study indicated that the reaction involves a C-sp(3)-Pd-IV(CF3) intermediate, which undergoes reductive elimination to afford a C-sp(3)-CF3 bond. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1021/ja210614y |
| 语种 | 英语 |
| WOS记录号 | WOS:000301084300035 |
| 公开日期 | 2013-08-22 |
| 源URL | [http://202.127.28.38/handle/331003/28033]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Mu X,Wu T,Wang HY,et al. Palladium-Catalyzed Oxidative Aryltrifluoromethylation of Activated Alkenes at Room Temperature[J]. J. Am. Chem. Soc.,2012,134(2):878-881. |
| APA | 慕欣,吴涛,王昊阳,郭寅龙,&刘国胜.(2012).Palladium-Catalyzed Oxidative Aryltrifluoromethylation of Activated Alkenes at Room Temperature.J. Am. Chem. Soc.,134(2),878-881. |
| MLA | 慕欣,et al."Palladium-Catalyzed Oxidative Aryltrifluoromethylation of Activated Alkenes at Room Temperature".J. Am. Chem. Soc. 134.2(2012):878-881. |
入库方式： OAI收割
来源：上海有机化学研究所
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