Syntheses, Structures, and Photoluminescent Properties of Coordination Polymers Based on 1,4-Bis(imidazol-l-yl-methyl)benzene and Various Aromatic Dicarboxylic Acids
文献类型：期刊论文
| 作者 | Song XZ ; Song SY ; Qin C ; Su SQ ; Zhao SN ; Zhu M ; Hao ZM ; Zhang HJ |
| 刊名 | crystal growth & design
 |
| 出版日期 | 2012 |
| 卷号 | 12期号:1页码:253-263 |
| 关键词 | METAL-ORGANIC FRAMEWORKS HETEROGENEOUS ASYMMETRIC CATALYSIS FLEXIBLE BIS(IMIDAZOLE) LIGANDS 2D POLYROTAXANE NETWORK PARALLEL INTERPENETRATION CRYSTAL-STRUCTURES GAS-ADSORPTION COMPLEXES NETS ARCHITECTURES |
| ISSN号 | 1528-7483 |
| 通讯作者 | zhang hj |
| 中文摘要 | nine coordination polymers, formulated as {[zn(pbdc)(bix)](dmf)(2)}(n) (1), {[co(p-bdc)(bix)](dmf)(2)}(n) (2), {[cd(p-bdc)(bix)](dmf)(2)}(n) (3), {[zn(bpdc)(bbc)](dmf)(3)}(n) (4), {[co(bpdc)(bix)](dmf)(3)}(n) (5), {[cd(m-bdc)(bix)(h2o)](dmf)}(n) (6), {[zn(m-bdc)(bix)] (solv)(x)}(n) (7), {[zn-2(m-bdc)(2)(bix)(2)](solv)(x)}(n) (8), and {[zn(m-bdc)(bix)](solv)(x)}(n) (9) (p-h(2)bdc = 1,4-benzenedicarboxylic acid, h(2)bpdc = biphenyl-4,4'-dicarboxylic acid, m-h(2)bdc = 1,3-benzenedicarboxylic acid), have been prepared by solvothermal reactions of the semirigid neutral ligand 1,4-bis(imidazol-1-yl-methyl)benzene (bix) with metal ions in the presence of various aromatic dicarboxylic acids. these complexes were characterized by fourier transform infrared (ft-ir) spectroscopy, elemental analysis, thermogravimetric analysis (tga), and single-crystal x-ray diffraction analysis. isostructural complexes 1 and 2 reveal a 3-fold interpenetrating three-dimensional (3d) framework with dia topological type. compound 3 exhibits a non-interpenetrating, highly undulating two-dimensional (2d) network with (4,4) topology. compounds 4 and 5 exhibit (6,3) layer structures consisting of hexagonal meshes and loops. compound 6, from the topological point of view, shows the same (4,4) topology as compound 3; however interestingly all the layers can be divided into pairs in the overall network. complex 7 also possesses a 3-fold interpenetrated 3d dia framework similar to 1 and 2. compound 8 comprises two independent 2d (4,8(2)) nets that interpenetrate in a parallel manner. non-interpenetrating 2d (4,4) layers are also observed in compound 9 that are further packed into a 3d framework featuring one-dimensional (1d) channels. the structural diversity of nine coordination polymers indicates that the structures can be tuned by metal ions, various ditopic carboxylate anions, and changeable conformations of neutral ligand. in addition, photoluminescent properties of four coordination polymers were also investigated in this paper. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000298726300036 |
| 公开日期 | 2013-09-03 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/48740]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Song XZ,Song SY,Qin C,et al. Syntheses, Structures, and Photoluminescent Properties of Coordination Polymers Based on 1,4-Bis(imidazol-l-yl-methyl)benzene and Various Aromatic Dicarboxylic Acids[J]. crystal growth & design,2012,12(1):253-263. |
| APA | Song XZ.,Song SY.,Qin C.,Su SQ.,Zhao SN.,...&Zhang HJ.(2012).Syntheses, Structures, and Photoluminescent Properties of Coordination Polymers Based on 1,4-Bis(imidazol-l-yl-methyl)benzene and Various Aromatic Dicarboxylic Acids.crystal growth & design,12(1),253-263. |
| MLA | Song XZ,et al."Syntheses, Structures, and Photoluminescent Properties of Coordination Polymers Based on 1,4-Bis(imidazol-l-yl-methyl)benzene and Various Aromatic Dicarboxylic Acids".crystal growth & design 12.1(2012):253-263. |
入库方式： OAI收割
来源：长春应用化学研究所
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