Study on the electrochemical properties of cubic ordered mesoporous carbon for supercapacitors
文献类型:期刊论文
作者 | Yan XB(阎兴斌)![]() ![]() ![]() ![]() |
刊名 | Journal of Power Sources
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出版日期 | 2011 |
卷号 | 196页码:10472-10478 |
关键词 | Ordered mesoporous carbon Cubic mesoporous carbon Chemical modification Specific capacitance Supercapacitor |
ISSN号 | 0378-7753 |
通讯作者 | 阎兴斌 |
中文摘要 | Highly ordered, three-dimensional (3D) cubic mesoporous carbon CMK-8 is prepared by a facile nanocast- ing approach using cubic mesoporous silica KIT-6 as starting template. Afterwards, in order to increase the active sites of surface electrochemical reactions and promote the wettability in aqueous electrolyte, a chemical surface modification is carried out on the CMK-8 by nitric acid treatment. Two electrodes are prepared from the CMK-8 and the acid-modified CMK-8 (H-CMK-8) and used as the active materials for supercapacitors. The unique 3D mesoporous network combined with high specific surface area makes the nano-channel surfaces of the CMK-8 carbon favorable for charging the electric double-layer, resulting in that the CMK-8 and the H-CMK-8 electrodes both show well supercapacitive properties. Furthermore, the specific capacitance of the CMK-8 can be further improved by acid treatment, so that the H-CMK-8 exhibits the largest specific capacitance of 246 F g−1 at a current density of 0.625 A g−1 in 2 M KOH elec- trolyte. Also, the two carbon electrodes both exhibit good cycling stability and lifetime. Therefore, based on the above investigations, such CMK-8 carbon, especially H-CMK-8 carbon can be a potential candidate for supercapacitors. |
学科主题 | 材料科学与物理化学 |
收录类别 | SCI |
资助信息 | the Top Hundred Talents Program of Chinese Academy of Sciences;the National Nature Science Foundations of China (51005225);the Postdoctoral Science Foundation of China (20100480728) |
语种 | 英语 |
WOS记录号 | WOS:000296216600084 |
公开日期 | 2013-07-01 |
源URL | [http://210.77.64.217/handle/362003/3252] ![]() |
专题 | 兰州化学物理研究所_固体润滑国家重点实验室 |
通讯作者 | Yan XB(阎兴斌); Yan XB(阎兴斌) |
推荐引用方式 GB/T 7714 | Yan XB,Yang J,Xue QJ,et al. Study on the electrochemical properties of cubic ordered mesoporous carbon for supercapacitors[J]. Journal of Power Sources,2011,196:10472-10478. |
APA | 阎兴斌,杨杰,薛群基,&阎兴斌.(2011).Study on the electrochemical properties of cubic ordered mesoporous carbon for supercapacitors.Journal of Power Sources,196,10472-10478. |
MLA | 阎兴斌,et al."Study on the electrochemical properties of cubic ordered mesoporous carbon for supercapacitors".Journal of Power Sources 196(2011):10472-10478. |
入库方式: OAI收割
来源:兰州化学物理研究所
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