Solid-state NMR studies of the acidity of functionalized metal-organic framework UiO-66 materials
文献类型：期刊论文
| 作者 | Tang, Jing1,2; Li, Shenhui2; Chui, Yueying2; Xiao, Yuqing1,2; Xu, Jun2; Deng, Feng2 |
| 刊名 | MAGNETIC RESONANCE IN CHEMISTRY
 |
| 出版日期 | 2019-07-31 |
| 页码 | 8 |
| 关键词 | acidity characterization metal-organic framework solid state NMR UiO-66 |
| ISSN号 | 0749-1581 |
| DOI | 10.1002/mrc.4923 |
| 英文摘要 | The acid strength of metal-organic frameworks plays a key role in their catalytic performance such as activity and selectivity during catalytic reactions. Solid-state nuclear magnetic resonance in combination with probe molecules including 2-C-13-acetone and pyridine-d(5) was employed to characterize the acid strength of UiO-66-X (X = -H, -2COOH, -SO3H). It was found that after introduction of the functional groups, the acid strength of UiO-66-2COOH and UiO-66-SO3H is considerably enhanced compared with that of parent UiO-66, with that of the former being similar to that of zeolite H-ZSM-5, and with that of the latter being slightly stronger than that of the former. Even though the acid density can efficiently be modified through changing the relative ratio in multivariate functionalized UiO-66-X, no significant alternation for the acid strength could be discerned in the MTV-UiO-66-X compared with acidic same-link counterpart. Theoretical calculations were employed to further confirm the acid strength of UiO-66-SO3H and UiO-66-2COOH. |
| WOS关键词 | C-13 CHEMICAL-SHIFT ; IN-SITU NMR ; CATALYSTS ; CHEMISTRY ; ZEOLITES ; STRENGTH ; CO2 ; ACETONE ; PROBE |
| 资助项目 | National Natural Science Foundation of China[21773295] ; National Natural Science Foundation of China[21733013] |
| WOS研究方向 | Chemistry ; Spectroscopy |
| 语种 | 英语 |
| WOS记录号 | WOS:000478754900001 |
| 出版者 | WILEY |
| 资助机构 | National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/14704]  |
| 专题 | 中国科学院武汉物理与数学研究所 |
| 通讯作者 | Li, Shenhui; Deng, Feng |
| 作者单位 | 1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, State Key Lab Magnet Resonance & Atom & Mol Phys, Natl Ctr Magnet Resonance Wuhan, CAS Key Lab Magnet Resonance Biol Syst,Wuhan Inst, Wuhan 430071, Hubei, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tang, Jing,Li, Shenhui,Chui, Yueying,et al. Solid-state NMR studies of the acidity of functionalized metal-organic framework UiO-66 materials[J]. MAGNETIC RESONANCE IN CHEMISTRY,2019:8. |
| APA | Tang, Jing,Li, Shenhui,Chui, Yueying,Xiao, Yuqing,Xu, Jun,&Deng, Feng.(2019).Solid-state NMR studies of the acidity of functionalized metal-organic framework UiO-66 materials.MAGNETIC RESONANCE IN CHEMISTRY,8. |
| MLA | Tang, Jing,et al."Solid-state NMR studies of the acidity of functionalized metal-organic framework UiO-66 materials".MAGNETIC RESONANCE IN CHEMISTRY (2019):8. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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