photodissociationphotoionizationprocessesofchlorobromomethaneinducedbyfemtosecondlaserpulseswithpumpprobescheme
文献类型:期刊论文
作者 | ZHANG Feng; WEI ZhengRong; CAO ZhenZhou; ZHANG ChangHua; ZHANG Bing |
刊名 | chinesesciencebulletin
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出版日期 | 2008 |
卷号 | 53期号:5页码:681 |
ISSN号 | 1001-6538 |
英文摘要 | The photodissociation/photoionization processes of chlorobromomethane (CH2BrCl) induced by femtosecond laser pulses have been investigated using pump-probe scheme combined with the time-of-flight mass spectra. The dominate photoproducts are observed at different delay time of the pump (400 nm) and probe (800 nm) pulses and the corresponding time-dependence of them is obtained. The results show that the decaying time of the molecule CH2BrCl in the A-band is in the 100 fs. The decaying tendencies of the fragment ions (CH2Cl+ and CH2Br+) and the parent ion (CH2BrCl+) are almost the same and the relative ratios of the yields of them keep constant during the delay time of 0 to 150 fs. These facts suggest that the fragment ions come from the fragmentation of the parent ions in excited electronic states. The probabilities to form CH2Cl+ and CH2Br+ are obtained from the relative ratio of the ion intensity and are about 71.6% and 14.2%, respectively. |
语种 | 英语 |
源URL | [http://ir.wipm.ac.cn/handle/112942/15291] ![]() |
专题 | 中国科学院武汉物理与数学研究所 |
作者单位 | 中国科学院武汉物理与数学研究所 |
推荐引用方式 GB/T 7714 | ZHANG Feng,WEI ZhengRong,CAO ZhenZhou,et al. photodissociationphotoionizationprocessesofchlorobromomethaneinducedbyfemtosecondlaserpulseswithpumpprobescheme[J]. chinesesciencebulletin,2008,53(5):681. |
APA | ZHANG Feng,WEI ZhengRong,CAO ZhenZhou,ZHANG ChangHua,&ZHANG Bing.(2008).photodissociationphotoionizationprocessesofchlorobromomethaneinducedbyfemtosecondlaserpulseswithpumpprobescheme.chinesesciencebulletin,53(5),681. |
MLA | ZHANG Feng,et al."photodissociationphotoionizationprocessesofchlorobromomethaneinducedbyfemtosecondlaserpulseswithpumpprobescheme".chinesesciencebulletin 53.5(2008):681. |
入库方式: OAI收割
来源:武汉物理与数学研究所
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