thereactionofmolybdenumwith23dihydroxynaphthalene
文献类型：期刊论文
| 作者 | XiaoMing Lu1; XiuHuan Pei1; XiaoJun Wang1; ChaoHui Ye2 |
| 刊名 | chinesejournalofchemistry
 |
| 出版日期 | 2007 |
| 卷号 | 25期号:4页码:448 |
| ISSN号 | 1001-604X |
| 英文摘要 | H2N(CH2)3NH32MoO2(C10H6O2)2 (1) was synthesized by the reaction of (n-Bu4N)4Mo8O26 with 2,3-dihydroxynaphthalene in the mixed solvent of CH3OH, CH3CN and 1,3-propanediamine. (C5H11N2)2- H2N(CH2)3NH2MoO2(C10H6O2)2 (2) was obtained by the reaction of Na2MoO4·2H2O with 2,3-dihydroxy- naphthalene in the same solvent above. Both of the complexes possess complex anion Mo(VI)O2(OC10H6O)22- which shows pseudo-octahedrally coordinated fashion, while the counterions are two protonated 1,3-propanedia- mine in complex 1 and (C5H11N2)+ in complex 2. (C5H11N2)+ is the byproduct of reaction 2, which results from combination of acetonitrile with 1,3-propanediamine. Packing diagrams of the two complexes are also different. There is anti-parallel-aligned-double-meso-bilayer unit in complex 1. However there are four chiral anions arranged in anticlockwise orientation in complex 2. |
| 语种 | 英语 |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/18604]  |
| 专题 | 中国科学院武汉物理与数学研究所 |
| 作者单位 | 1.首都师范大学 2.中国科学院武汉物理与数学研究所 |
| 推荐引用方式 GB/T 7714 | XiaoMing Lu,XiuHuan Pei,XiaoJun Wang,et al. thereactionofmolybdenumwith23dihydroxynaphthalene[J]. chinesejournalofchemistry,2007,25(4):448. |
| APA | XiaoMing Lu,XiuHuan Pei,XiaoJun Wang,&ChaoHui Ye.(2007).thereactionofmolybdenumwith23dihydroxynaphthalene.chinesejournalofchemistry,25(4),448. |
| MLA | XiaoMing Lu,et al."thereactionofmolybdenumwith23dihydroxynaphthalene".chinesejournalofchemistry 25.4(2007):448. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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