Adsorptive removal of new methylene blue from water by treated Malus domestica sawdust as a low cost biosorbent - equilibrium, kinetics and thermodynamic studies
文献类型:期刊论文
作者 | Naz, Saira4; Alam, Sultan3; Rehan, Kamran2; Sultana, Sabiha1 |
刊名 | DESALINATION AND WATER TREATMENT
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出版日期 | 2019-10-01 |
卷号 | 166页码:72-82 |
关键词 | New Methylene blue Sawdust Malus domestica Adsorption Kinetics Isotherms Adsorption Thermodynamics |
ISSN号 | 1944-3994 |
DOI | 10.5004/dwt.2019.24591 |
英文摘要 | In this study the adsorption of New Methylene blue (Basic blue 24) on sawdust of Malus domestica was investigated. The sawdust was chemically treated to enhance the adsorption capacity. Adsorption experiments were performed at different temperatures ranging from 20-40 degrees C on both raw and treated sawdust samples. The residual concentration of the dye was determined by UV-Vis spectrophotometric technique. Effect of various reaction parameters like temperature, initial dye concentration, equilibration time and pH was studied. Sawdust was characterized by BET, FTIR, Scanning electron microscopy (SEM), and Energy dispersive spectroscopy (EDS) techniques. Adsorption kinetics was interpreted using intra particle diffusion and Bangham models and both models were found to best describe the sorption of New Methylene blue onto M. domestica. Thermodynamic parameters like Delta E degrees, Delta H degrees, Delta S degrees and Delta G degrees were calculated from the adsorption kinetics data. The data show that the adsorption is an endothermic process. The negative value of entropy shows that the dye molecules take an oriented position on the adsorbent surface. Adsorption data fitted well with Langmuir, Freundlich and Temkin adsorption isotherms. All results clarify that M. domestica sawdust is a useful cheap adsorbent for removing basic dyes. |
WOS关键词 | AQUEOUS-SOLUTION ; SUGARCANE BAGASSE ; DYE ; BATCH ; BIOSORPTION ; ADSORBENTS ; VIOLET ; ORANGE |
WOS研究方向 | Engineering ; Water Resources |
语种 | 英语 |
WOS记录号 | WOS:000489318500008 |
出版者 | DESALINATION PUBL |
源URL | [http://ir.wipm.ac.cn/handle/112942/21394] ![]() |
专题 | 中国科学院武汉物理与数学研究所 |
通讯作者 | Naz, Saira |
作者单位 | 1.Islamia Coll Univ, Dept Chem, Peshawar, Pakistan 2.Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Hubei, Peoples R China 3.Univ Malakand, Dept Chem, Chakdara, Dir L, Pakistan 4.Univ Peshawar, Inst Chem Sci, Khyber Pakhtunkhwa, Pakistan |
推荐引用方式 GB/T 7714 | Naz, Saira,Alam, Sultan,Rehan, Kamran,et al. Adsorptive removal of new methylene blue from water by treated Malus domestica sawdust as a low cost biosorbent - equilibrium, kinetics and thermodynamic studies[J]. DESALINATION AND WATER TREATMENT,2019,166:72-82. |
APA | Naz, Saira,Alam, Sultan,Rehan, Kamran,&Sultana, Sabiha.(2019).Adsorptive removal of new methylene blue from water by treated Malus domestica sawdust as a low cost biosorbent - equilibrium, kinetics and thermodynamic studies.DESALINATION AND WATER TREATMENT,166,72-82. |
MLA | Naz, Saira,et al."Adsorptive removal of new methylene blue from water by treated Malus domestica sawdust as a low cost biosorbent - equilibrium, kinetics and thermodynamic studies".DESALINATION AND WATER TREATMENT 166(2019):72-82. |
入库方式: OAI收割
来源:武汉物理与数学研究所
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