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An Ultrastable Metal Azolate Framework with Binding Pockets for Optimal Carbon Dioxide Capture

文献类型：期刊论文

作者Wang, Zhi-Shuo3,4,5; Li, Mian3,4,5; Peng, Yun-Lei2; Zhang, Zhenjie2; Chen, Wei1; Huang, Xiao-Chun3,4,5
刊名ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
出版日期2019-09-24
页码7
关键词binding pockets carbon capture metal-organic frameworks stability zeolite analogues
ISSN号1433-7851
DOI10.1002/anie.201909046
英文摘要In the evolution of metal-organic frameworks (MOFs) for carbon capture, a lasting challenge is to strike a balance between high uptake capacity/selectivity and low energy cost for regeneration. Meanwhile, these man-made materials have to survive from practical demands such as stability under harsh conditions and feasibility of scale-up synthesis. Reported here is a new MOF, Zn(imPim) (aka. MAF-stu-1), with an imidazole derivative ligand, featuring binding pockets that can accommodate CO2 molecules in a fit-like-a-glove manner. Such a high degree of shape complementarity allows direct observation of the loaded CO2 in the pockets, and warrants its optimal carbon capture performances exceeding the best-performing MOFs nowadays. Coupled with the record thermal (up to 680 degrees C) and chemical stability, as well as rapid large-scale production, both encoded in the material design, Zn(imPim) represents a most competitive candidate to tackle the immediate problems of carbon dioxide capture.
WOS关键词ORGANIC FRAMEWORKS ; CO2 ; ADSORPTION ; CHEMISTRY ; ISOMERS ; DESIGN ; AIR
资助项目NSFC[21571122] ; National Basic Research Program of China (973 Program)[2013CB834803] ; Department of Education in Guangdong Province[2014KCXTD012]
WOS研究方向Chemistry
语种英语
WOS记录号WOS:000487457900001
出版者WILEY-V C H VERLAG GMBH
资助机构NSFC ; NSFC ; National Basic Research Program of China (973 Program) ; National Basic Research Program of China (973 Program) ; Department of Education in Guangdong Province ; Department of Education in Guangdong Province ; NSFC ; NSFC ; National Basic Research Program of China (973 Program) ; National Basic Research Program of China (973 Program) ; Department of Education in Guangdong Province ; Department of Education in Guangdong Province ; NSFC ; NSFC ; National Basic Research Program of China (973 Program) ; National Basic Research Program of China (973 Program) ; Department of Education in Guangdong Province ; Department of Education in Guangdong Province ; NSFC ; NSFC ; National Basic Research Program of China (973 Program) ; National Basic Research Program of China (973 Program) ; Department of Education in Guangdong Province ; Department of Education in Guangdong Province
源URL[http://ir.wipm.ac.cn/handle/112942/21478]  
专题中国科学院武汉物理与数学研究所
通讯作者Huang, Xiao-Chun
作者单位1.Chinese Acad Sci, State Key Lab Magnet Resonance & Atom & Mol Phys, Key Lab Magnet Resonance Biol Syst, Wuhan Inst Phys & Math,Natl Ctr Magnet Resonance, Wuhan 430071, Hubei, Peoples R China
2.Nankai Univ, Coll Chem, Tianjin 300071, Peoples R China
3.Chem & Chem Engn Guangdong Lab, Shantou 515031, Peoples R China
4.Shantou Univ, Key Lab Preparat & Applicat Ordered Struct Mat Gu, Shantou 515063, Guangdong, Peoples R China
5.Shantou Univ, Dept Chem, Shantou 515063, Guangdong, Peoples R China
推荐引用方式
GB/T 7714		 Wang, Zhi-Shuo,Li, Mian,Peng, Yun-Lei,et al. An Ultrastable Metal Azolate Framework with Binding Pockets for Optimal Carbon Dioxide Capture[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2019:7.
APA Wang, Zhi-Shuo,Li, Mian,Peng, Yun-Lei,Zhang, Zhenjie,Chen, Wei,&Huang, Xiao-Chun.(2019).An Ultrastable Metal Azolate Framework with Binding Pockets for Optimal Carbon Dioxide Capture.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,7.
MLA Wang, Zhi-Shuo,et al."An Ultrastable Metal Azolate Framework with Binding Pockets for Optimal Carbon Dioxide Capture".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019):7.

入库方式： OAI收割

来源：武汉物理与数学研究所

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