Better scCO(2) Foaming of Polypropylene via Earlier Crystallization with the Addition of Composite Nucleating Agent
文献类型:期刊论文
作者 | Yang, CG; Xing, Z; Wang, MH; Zhao, Q; Wang, ML; Zhang, MJ; Wu, GZ |
刊名 | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
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出版日期 | 2018 |
卷号 | 57期号:46页码:15916-15923 |
关键词 | PRESSURE-INDUCED-FLOW FACILE PREPARATION PARTICLE-SIZE BEHAVIOR DENSITY NANOCOMPOSITES STRENGTH MORPHOLOGY NANOFIBERS RADIATION |
ISSN号 | 0888-5885 |
DOI | 10.1021/acs.iecr.8b03866 |
文献子类 | 期刊论文 |
英文摘要 | A method of earlier crystallization was applied to prepare high-performance polypropylene (PP) foam using supercritical CO2 (scCO(2)) with the addition of a composite nucleating agent (CNA). Increased crystallization point and decreased crystal size of PP were obtained in the presence of CNA. Earlier crystallization induced cell formation in an early stage of foaming; this, combined with enhanced heterogeneous nucleation caused by microcrystal growth, resulted in well-defined cellular structure. The cell size of PP/CNA foam decreased from 87 to 30 mu m, and the cell density was more than 20 times that of the neat PP foam. Moreover, the first compression stress of PP/CNA foam increased from 125 to 180 kPa compared to neat PP foam. We proposed that earlier crystallization promoted the emergence of a large number of microcrystals at the beginning of the foaming process, which effectively suppressed cell growth and prevented cell rupture and collapse. |
语种 | 英语 |
源URL | [http://ir.sinap.ac.cn/handle/331007/30862] ![]() |
专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
作者单位 | 1.Chinese Acad Sci, Shanghai Inst Appl Phys, Jialuo Rd 2019, Shanghai 201800, Peoples R China 2.ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 200031, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Yang, CG,Xing, Z,Wang, MH,et al. Better scCO(2) Foaming of Polypropylene via Earlier Crystallization with the Addition of Composite Nucleating Agent[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2018,57(46):15916-15923. |
APA | Yang, CG.,Xing, Z.,Wang, MH.,Zhao, Q.,Wang, ML.,...&Wu, GZ.(2018).Better scCO(2) Foaming of Polypropylene via Earlier Crystallization with the Addition of Composite Nucleating Agent.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,57(46),15916-15923. |
MLA | Yang, CG,et al."Better scCO(2) Foaming of Polypropylene via Earlier Crystallization with the Addition of Composite Nucleating Agent".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 57.46(2018):15916-15923. |
入库方式: OAI收割
来源:上海应用物理研究所
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