Evidence of the Strong Metal Support Interaction in a Palladium-Ceria Hybrid Electrocatalyst for Enhancement of the Hydrogen Evolution Reaction
文献类型：期刊论文
| 作者 | Gao, TY; Yang, J; Nishijima, M; Miller, HA; Vizza, F; Gu, HY; Chen, HQ; Hu, YF; Jiang, Z; Wang, L |
| 刊名 | JOURNAL OF THE ELECTROCHEMICAL SOCIETY
 |
| 出版日期 | 2018 |
| 卷号 | 165期号:14页码:F1147-F1153 |
| 关键词 | OXYGEN REDUCTION REACTION MEMBRANE FUEL-CELLS CO OXIDATION ETHANOL ELECTROOXIDATION PLATINUM NANOPARTICLES CATALYTIC-ACTIVITY MOLYBDENUM BORIDE DOPED CARBON PD EFFICIENT |
| ISSN号 | 0013-4651 |
| DOI | 10.1149/2.0351814jes |
| 文献子类 | 期刊论文 |
| 英文摘要 | A facile two-step method was developed to synthesize a novel Pd/CeO2/C hybrid electrocatalyst for the hydrogen evolution reaction (HER) in alkaline media. Compared to Pd/C, CeO2/C, and a physical mixture of Pd/C and CeO2/C, the Pd/CeO2 C hybrid exhibited a superior HER electrocatalytic activity. Stable performance of the Pd/CeO2/C hybrid was achieved during a 12 h chronopotentiometry test at 15 mA cm(-2). The improved HER activity and stability can be attributed to the presence of CeO2 not only as a support for anchoring and stabilizing of Pd nanoparticles, but also via strong interaction between Pd and CeO2. Here an intimate contact between Pd and CeO2 nanoparticles and the strong metal support interaction were demonstrated by high resolution transmission electron microscopy (HR-TEM) and X-ray absorption spectroscopy (XAS). The electron transfer from Pd to CeO2 that results in Pd in the oxidized form was also shown by X-ray photoelectron spectroscopy (XPS). The XAS measurements additionally demonstrated that the surface Pd was partially oxidized to Pd oxide, and the formation of a plausible Pd-O-Ce structure in the Pd/CeO2/C hybrid. (C) 2018 The Electrochemical Society. |
| 语种 | 英语 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/30940]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 作者单位 | 1.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Shanghai 201204, Peoples R China 2.Zhejiang Univ, Coll Chem & Biol Engn, Zhejiang Prov Key Lab Adv Chem Engn Manufacture T, Hangzhou 310027, Zhejiang, Peoples R China 3.Zhejiang Univ, Coll Chem & Biol Engn, Minist Educ, Key Lab Biomass Chem Engn, Hangzhou 310027, Zhejiang, Peoples R China 4.Tohoku Univ, Electron Microscopy Ctr, Sendai, Miyagi 9808577, Japan 5.ICCOM CNR, Polo Sci Area CNR, Inst Chem Organometall Cpds, I-50019 Sesto Fiorentino, Italy 6.Canadian Light Source, Saskatoon, SK S7N 2V3, Canada 7.Cent China Normal Univ, Coll Phys Sci & Technol, Inst Nanosci & Nanotechnol, Wuhan 430079, Hubei, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gao, TY,Yang, J,Nishijima, M,et al. Evidence of the Strong Metal Support Interaction in a Palladium-Ceria Hybrid Electrocatalyst for Enhancement of the Hydrogen Evolution Reaction[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY,2018,165(14):F1147-F1153. |
| APA | Gao, TY.,Yang, J.,Nishijima, M.,Miller, HA.,Vizza, F.,...&He, QG.(2018).Evidence of the Strong Metal Support Interaction in a Palladium-Ceria Hybrid Electrocatalyst for Enhancement of the Hydrogen Evolution Reaction.JOURNAL OF THE ELECTROCHEMICAL SOCIETY,165(14),F1147-F1153. |
| MLA | Gao, TY,et al."Evidence of the Strong Metal Support Interaction in a Palladium-Ceria Hybrid Electrocatalyst for Enhancement of the Hydrogen Evolution Reaction".JOURNAL OF THE ELECTROCHEMICAL SOCIETY 165.14(2018):F1147-F1153. |
入库方式： OAI收割
来源：上海应用物理研究所
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