High pressure effects on hydrate Cu-BTC investigated by vibrational spectroscopy and synchrotron X-ray diffraction
文献类型：期刊论文
| 作者 | Dong, ZH; Mi, ZY; Shi, WG; Jiang, H; Zheng, Y; Yang, K |
| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2017 |
| 卷号 | 7期号:87页码:55504-55512 |
| 关键词 | METAL-ORGANIC-FRAMEWORK DRUG-DELIVERY IMIDAZOLATE FRAMEWORK BOND REARRANGEMENT FTIR SPECTROSCOPY SINGLE-CRYSTAL CO2 ADSORPTION MOFS STORAGE CU-3(1,3,5-BENZENETRICARBOXYLATE)(2) |
| ISSN号 | 2046-2069 |
| DOI | 10.1039/c7ra11843k |
| 文献子类 | 期刊论文 |
| 英文摘要 | The high pressure behaviors of hydrate Cu-BTC metal-organic framework (MOF) in terms of phase stability, compressibility and reversibility were investigated in situ by synchrotron X-ray powder diffraction as well as vibrational spectroscopy. Two phase transitions, caused by the interaction of water and the sample framework, were revealed by the vibrational spectroscopies. Compressibility of the hydrate Cu-BTC also displays soft and hard regimes, which is the same scenario as non-hydrate Cu-BTC with a pressure transmitting medium. It is further confirmed that the residual water molecules in hydrate Cu-BTC can serve as a pressure transmitting medium with small molecule size under high pressure. Our results not only prove the high stability of Cu-BTC but also provide spectroscopic evidence for the interactions taking place between the guest molecules and the sample framework. Such findings could provide further guidelines for improving Cu-BTC's absorption and storage abilities. |
| 语种 | 英语 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/30966]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 作者单位 | 1.Peking Univ, Sch Earth & Space Sci, Beijing 100871, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Shanghai 201204, Peoples R China 3.Northeast Petr Univ, Coll Chem & Chem Engn, Daqing 163318, Peoples R China |
| 推荐引用方式 GB/T 7714 | Dong, ZH,Mi, ZY,Shi, WG,et al. High pressure effects on hydrate Cu-BTC investigated by vibrational spectroscopy and synchrotron X-ray diffraction[J]. RSC ADVANCES,2017,7(87):55504-55512. |
| APA | Dong, ZH,Mi, ZY,Shi, WG,Jiang, H,Zheng, Y,&Yang, K.(2017).High pressure effects on hydrate Cu-BTC investigated by vibrational spectroscopy and synchrotron X-ray diffraction.RSC ADVANCES,7(87),55504-55512. |
| MLA | Dong, ZH,et al."High pressure effects on hydrate Cu-BTC investigated by vibrational spectroscopy and synchrotron X-ray diffraction".RSC ADVANCES 7.87(2017):55504-55512. |
入库方式： OAI收割
来源：上海应用物理研究所
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