Immobilization of Alkali Metal Fluorides via Recrystallization in a Cationic Lamellar Material, [Th(MoO4)(H2O)(4)Cl]Cl center dot H2O
文献类型：期刊论文
| 作者 | Lin, J; Bao, HL; Qie, MY; Silver, MA; Yue, ZH; Li, XY; Zhu, L; Wang, XM; Zhang, LJ; Wang, JQ |
| 刊名 | INORGANIC CHEMISTRY
 |
| 出版日期 | 2018 |
| 卷号 | 57期号:12页码:6778-6782 |
| 关键词 | BAND WHITE-LIGHT THORIUM MOLYBDATES CRYSTAL TRANSFORMATION ORGANIC FRAMEWORK LAYERED MATERIALS SINGLE-CRYSTAL ANION-EXCHANGE HIGH-CAPACITY COORDINATION CERIUM(IV) |
| ISSN号 | 0020-1669 |
| DOI | 10.1021/acs.inorgchem.8b00954 |
| 文献子类 | 期刊论文 |
| 英文摘要 | Searching for cationic extended materials with a capacity for anion exchange resulted in a unique thorium molybdate chloride (TMC) with the formula of [Th(MoO4)(H2O)(4)Cl]Cl center dot H2O. The structure of TMC is composed of zigzagging cationic layers [Th(MoO4)-(H2O)(4)Cl](+) with Cl- as interlamellar charge-balancing anions. Instead of performing ion exchange, alkali thorium fluorides were formed after soaking TMC in AF (A = Na, K, and Cs) solutions. The mechanism of AF immobilization is elucidated by the combination of SEM-EDS, PXRD, FTIR, and EXAFS spectroscopy. It was observed that four water molecules coordinating with the Th4+ center in TMC are vulnerable to competition with F-, due to the formation of more favorable Th-F bonds compared to Th-OH2. This leads to a single crystal-to-polycrystalline transformation via a pathway of recrystallization to form alkali thorium fluorides. |
| 语种 | 英语 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/30977]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 作者单位 | 1.Soochow Univ, Sch Radiol & Interdisciplinary Sci RAD X, 199 Renai Rd, Suzhou 215123, Peoples R China 2.Univ Chinese Acad Sci, 2019 Jia Luo Rd, Shanghai 201800, Peoples R China 3.Soochow Univ, Jiangsu Higher Educ Inst, Collaborat Innovat Ctr Radiat Med, 199 Renai Rd, Suzhou 215123, Peoples R China 4.Chinese Acad Sci, Shanghai Inst Appl Phys, 2019 Jia Luo Rd, Shanghai 201800, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lin, J,Bao, HL,Qie, MY,et al. Immobilization of Alkali Metal Fluorides via Recrystallization in a Cationic Lamellar Material, [Th(MoO4)(H2O)(4)Cl]Cl center dot H2O[J]. INORGANIC CHEMISTRY,2018,57(12):6778-6782. |
| APA | Lin, J.,Bao, HL.,Qie, MY.,Silver, MA.,Yue, ZH.,...&Wang, JQ.(2018).Immobilization of Alkali Metal Fluorides via Recrystallization in a Cationic Lamellar Material, [Th(MoO4)(H2O)(4)Cl]Cl center dot H2O.INORGANIC CHEMISTRY,57(12),6778-6782. |
| MLA | Lin, J,et al."Immobilization of Alkali Metal Fluorides via Recrystallization in a Cationic Lamellar Material, [Th(MoO4)(H2O)(4)Cl]Cl center dot H2O".INORGANIC CHEMISTRY 57.12(2018):6778-6782. |
入库方式： OAI收割
来源：上海应用物理研究所
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