Influence of alpha-Al2O3 and AlF(3 )on pyrohydrolysis of Li3AlF6
文献类型：期刊论文
| 作者 | Peng, J; Zheng, XB; Liu, YX; Zhang, L |
| 刊名 | NUCLEAR SCIENCE AND TECHNIQUES
 |
| 出版日期 | 2018 |
| 卷号 | 29期号:9页码:- |
| 关键词 | FLUORIDE SEPARATION HALOGENS SYSTEM |
| ISSN号 | 1001-8042 |
| DOI | 10.1007/s41365-018-0465-2 |
| 文献子类 | 期刊论文 |
| 英文摘要 | In this study, Li3AlF6 was employed to simulate the molten salt LiF-BeF2 to explore its pyrohydrolysis behavior and that of its components, i.e., LiF and AlF3, respectively. The influence of the accelerators alpha-Al2O3 and AlF3 on the pyrohydrolysis of LiF and Li3AlF6 was investigated. Finally, the solid pyrohydrolytic products were characterized by means of X-ray diffraction, and the corresponding reaction mechanisms were proposed. These experimental results indicated that AlF3 was completely hydrolyzed to the corresponding oxide alpha-Al2O3 at 650 degrees C in 1 h, whereas the complete hydrolysis of LiF and Li3AlF6 required the assistance of either alpha-Al2O3 or AlF3 under the same conditions. The influence of the accelerator alpha-Al2O3 and AlF3 on the pyrohydrolytic behavior of Li3AlF6 provides references for future research studies on the pyrohydrolysis of LiF-BeF2 and multi-component molten salts. |
| 语种 | 英语 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/30992]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 作者单位 | 1.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China 2.CAS Innovat Acad TMSR Energy Syst, Shanghai 201800, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Peng, J,Zheng, XB,Liu, YX,et al. Influence of alpha-Al2O3 and AlF(3 )on pyrohydrolysis of Li3AlF6[J]. NUCLEAR SCIENCE AND TECHNIQUES,2018,29(9):-. |
| APA | Peng, J,Zheng, XB,Liu, YX,&Zhang, L.(2018).Influence of alpha-Al2O3 and AlF(3 )on pyrohydrolysis of Li3AlF6.NUCLEAR SCIENCE AND TECHNIQUES,29(9),-. |
| MLA | Peng, J,et al."Influence of alpha-Al2O3 and AlF(3 )on pyrohydrolysis of Li3AlF6".NUCLEAR SCIENCE AND TECHNIQUES 29.9(2018):-. |
入库方式： OAI收割
来源：上海应用物理研究所
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