Infrared Spectra of the SO2F2- Anion in Solid Argon and Neon
文献类型：期刊论文
| 作者 | Wei, R; Chen, XT; Gong, Y |
| 刊名 | JOURNAL OF PHYSICAL CHEMISTRY A
 |
| 出版日期 | 2018 |
| 卷号 | 122期号:38页码:7723-7729 |
| 关键词 | DENSITY-FUNCTIONAL THEORY ION-MOLECULE REACTIONS MATRIX-ISOLATION THEORETICAL INVESTIGATIONS VIBRATIONAL FREQUENCIES POLYFLUORIDE ANIONS SULFUR-FLUORIDE RARE-GASES COMPLEXES THERMOCHEMISTRY |
| ISSN号 | 1089-5639 |
| DOI | 10.1021/acs.jpca.8b07756 |
| 文献子类 | 期刊论文 |
| 英文摘要 | Sulfonyl fluoride anion (SO2F2-) was produced during codeposition of laser-ablated metal atoms, ions, and electrons with SO2F2 in argon and neon matrixes at 4 K. The structure of SO2F2- was determined by infrared spectroscopy and density functional theory calculations. On the basis of the experiments using (SO2F2)-S-34 and (SO2F2)-O-18 samples, the three absorptions at 1284.9, 1109.3, and 567.0 cm -l in argon and 1289.0, 1116.2, and 576.8 cm(-1) in neon were assigned to the antisymmetric and symmetric O-S-O stretching and SO2 wagging modes of SO2F2-, respectively. These assignments were further supported by frequency and isotopic frequency ratio calculations. The SO2F2- anion possesses a (2)A(1) ground state with nonplanar C2, symmetry. Compared with the neutral SO(2)F(2)molecule, dramatic increases in the S-F bond length (0.295 angstrom) and F-S-F bond angle (41.0 degrees) were found for the anion, which result from the S-F antibonding character of the singly occupied molecular orbital. The SO2F2- anion was formed via electron capture by SO2F2 in the gas phase before being deposited into the cryogenic matrix. The matrix environment stabilized this anion, but it was destroyed by UV-vis irradiation and presumably converted to the neutral SO2F2 molecule. |
| 语种 | 英语 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/30995]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 作者单位 | 1.Chinese Acad Sci, Shanghai Inst Appl Phys, Dept Radiochem, Shanghai 201800, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wei, R,Chen, XT,Gong, Y. Infrared Spectra of the SO2F2- Anion in Solid Argon and Neon[J]. JOURNAL OF PHYSICAL CHEMISTRY A,2018,122(38):7723-7729. |
| APA | Wei, R,Chen, XT,&Gong, Y.(2018).Infrared Spectra of the SO2F2- Anion in Solid Argon and Neon.JOURNAL OF PHYSICAL CHEMISTRY A,122(38),7723-7729. |
| MLA | Wei, R,et al."Infrared Spectra of the SO2F2- Anion in Solid Argon and Neon".JOURNAL OF PHYSICAL CHEMISTRY A 122.38(2018):7723-7729. |
入库方式： OAI收割
来源：上海应用物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。