Kinetics and Abnormal Inhibition of THF on Ethylene Hydrate Formation from Ice Powder Based on Conversion Rate
文献类型：期刊论文
| 作者 | Shi, WG; Qing, HX; Zhang, SS; Lu, XY; Wang, XF; Li, BX; Xu, XH; Liu, WG; Wang, J; Dong, ZH |
| 刊名 | CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
 |
| 出版日期 | 2018 |
| 卷号 | 39期号:9页码:1968-1975 |
| 关键词 | METHANE HYDRATE EQUILIBRIUM NUCLEATION DEPENDENCE DYNAMICS WATER |
| ISSN号 | 0251-0790 |
| DOI | 10.7503/cjcu20180234 |
| 文献子类 | 期刊论文 |
| 英文摘要 | The conversion rate of ice powder(alpha), as a key parameter on evaluation of hydrate formation from ice. gas interface, was calculated by using compressibility non-ideal gas equation. And the Avrami equation and the Arrhenius equation were combined to investigate the kinetic information and influence rule of temperature, pressure, and tetrahydrofuran(THF) on the synthesis of ethylene hydrate from ice. As a result, there is no induction period during the formation of ethylene hydrate from ice. And the ethylene hydrate is rapidly nucleated on the ice surface and grows in the one-dimensional direction with the same rate. The activation energy(E-a) of ethylene hydrate from ice powder is 21.28 kJ/mol at 260.05-269.75 K, which is much lower than that in aqueous phase. The final alpha is 19.20% under the initial ethylene pressure of 4.90 MPa and 269.75 K. The a rises with the pressure from 1.98 MPa to 4.90 MPa and temperature from 250.46 K to 269.75 K. And THF can reduce alpha and conversion efficiency of alpha, which can identify that THF has abnormal inhibition on the formation of ethylene hydrate from ice by molecular size effect. |
| 语种 | 英语 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/31008]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 作者单位 | 1.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Shanghai 201204, Peoples R China 2.Dalian Univ Technol, Sch Energy & Power Engn, Dalian 116024, Peoples R China 3.Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130023, Jilin, Peoples R China 4.Northeast Petr Univ, Coll Chem & Chem Engn, Daging 163318, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shi, WG,Qing, HX,Zhang, SS,et al. Kinetics and Abnormal Inhibition of THF on Ethylene Hydrate Formation from Ice Powder Based on Conversion Rate[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2018,39(9):1968-1975. |
| APA | Shi, WG.,Qing, HX.,Zhang, SS.,Lu, XY.,Wang, XF.,...&Dong, ZH.(2018).Kinetics and Abnormal Inhibition of THF on Ethylene Hydrate Formation from Ice Powder Based on Conversion Rate.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,39(9),1968-1975. |
| MLA | Shi, WG,et al."Kinetics and Abnormal Inhibition of THF on Ethylene Hydrate Formation from Ice Powder Based on Conversion Rate".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 39.9(2018):1968-1975. |
入库方式： OAI收割
来源：上海应用物理研究所
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