Sol-Gel Technology Plus Radiation Curing: A Novel and Facile Technique for Preparing Thick, Large-Area Hyperbranched Polysiloxane Hybrids
文献类型：期刊论文
| 作者 | Chen, SY; Zhuo, DX; Hu, JT |
| 刊名 | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
 |
| 出版日期 | 2018 |
| 卷号 | 57期号:31页码:10372-10378 |
| 关键词 | EPOXY-RESINS ADVANCED COMPOSITES THERMAL-PROPERTIES SURFACE-PROPERTIES CYANATE ESTER COATINGS POLYMERS POLYMERIZATION NANOCOMPOSITE KINETICS |
| ISSN号 | 0888-5885 |
| DOI | 10.1021/acs.iecr.8b01665 |
| 文献子类 | 期刊论文 |
| 英文摘要 | Large-scale shrinkages and holes are the two critical disadvantages of the silicone resin prepared by the sol- gel technology and cured via traditional processes. To simultaneously overcome both problems, sol-gel technology along with gamma-radiation curing is developed for preparing organic- inorganic hybrids with large size and thicknesses. A hyperbranched polysiloxane (H-PMAPS) is successfully synthesized through the controlling hydrolysis of 3-methacryloxypropyltrimethoxysilane and then is subjected to nuclear magnetic resonance (Si NMR) and Fourier transform infrared (FTIR) spectra to characterize its structure. Room-temperature radiation curing followed by thermal curing out-of-the-mold at 170 degrees C for 3 h is suitable for curing H-PMAPS (denoted as RC-T/PMAPS). The RC-T/PMAPS hybrid exhibits a homogeneous phase with a riverlike morphology, excellent thermal resistance, and dielectric properties and is optically transparent. These attractive features of the RC-T/PMAPS hybrid suggest that the new approach proposed here is suitable for cutting-edge industries to develop high-performance organic-inorganic hybrids. |
| 语种 | 英语 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/31113]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 作者单位 | 1.Quanzhou Normal Univ, Coll Chem Engn & Mat Sci, 398 Donghai St, Quanzhou 362000, Fujian, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Appl Phys, CAS Ctr Excellence TMSR Energy Syst, 2019 Jialuo Rd, Shanghai 201800, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, SY,Zhuo, DX,Hu, JT. Sol-Gel Technology Plus Radiation Curing: A Novel and Facile Technique for Preparing Thick, Large-Area Hyperbranched Polysiloxane Hybrids[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2018,57(31):10372-10378. |
| APA | Chen, SY,Zhuo, DX,&Hu, JT.(2018).Sol-Gel Technology Plus Radiation Curing: A Novel and Facile Technique for Preparing Thick, Large-Area Hyperbranched Polysiloxane Hybrids.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,57(31),10372-10378. |
| MLA | Chen, SY,et al."Sol-Gel Technology Plus Radiation Curing: A Novel and Facile Technique for Preparing Thick, Large-Area Hyperbranched Polysiloxane Hybrids".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 57.31(2018):10372-10378. |
入库方式： OAI收割
来源：上海应用物理研究所
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