Thermodynamic assessment of the SrBr2-MBr (M: alkali metal) binary systems
文献类型：期刊论文
| 作者 | Li, X; Xie, LD |
| 刊名 | CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY
 |
| 出版日期 | 2018 |
| 卷号 | 63期号:-页码:116-125 |
| 关键词 | ENERGY-STORAGE-SYSTEMS HALIDE-SYSTEMS BROMIDES |
| ISSN号 | 0364-5916 |
| DOI | 10.1016/j.calphad.2018.09.005 |
| 文献子类 | 期刊论文 |
| 英文摘要 | The phase diagrams of the SrBr2-MBr (M: alkali metal) binary systems based on phase equilibria and thermo-chemical data were evaluated and optimized using the CALPHAD method. The substitutional solution model was used to describe the Gibbs energies of all liquid phases. All intermediate compounds were handled to be stoichiometric of which the Gibbs energies comply with the Neumann-Kopp rule. Self-consistent datasets with all model parameters were developed, and thermodynamic properties of liquid phase (mixing enthalpy and activity) were also calculated for the whole range of compositions. Meanwhile, the empirical method based on ionic parameter function was successfully used to validate the mixing enthalpies calculated. Results manifest that the calculated results were in excellent agreement with the experimental values reported in the present work. By means of thermodynamic calculation, this database of strontium bromide system was used to predict the SrBr2-based multicomponent system with low melting points, which will design and prepare composite materials for low temperature thermal energy storage (TES). |
| 语种 | 英语 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/31150]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 作者单位 | 1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, X,Xie, LD. Thermodynamic assessment of the SrBr2-MBr (M: alkali metal) binary systems[J]. CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY,2018,63(-):116-125. |
| APA | Li, X,&Xie, LD.(2018).Thermodynamic assessment of the SrBr2-MBr (M: alkali metal) binary systems.CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY,63(-),116-125. |
| MLA | Li, X,et al."Thermodynamic assessment of the SrBr2-MBr (M: alkali metal) binary systems".CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY 63.-(2018):116-125. |
入库方式： OAI收割
来源：上海应用物理研究所
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