Diamondoid Frameworks via Supramolecular Coordination: Structural Characterization, Metallogel Formation, and Adsorption Study
文献类型：期刊论文
| 作者 | Cao, LP; Wang, PP; Miao, XR; Duan, HH; Wang, H; Dong, YH; Ma, R; Zhang, B; Wu, B; Li, XP |
| 刊名 | INORGANIC CHEMISTRY
 |
| 出版日期 | 2019 |
| 卷号 | 58期号:9页码:6268—6275 |
| ISSN号 | 0020-1669 |
| 关键词 | ORGANIC FRAMEWORKS CHEMISTRY METALLACYCLES NETWORKS COMPLEXES DISCRETE 2D |
| DOI | 10.1021/acs.inorgchem.9b00484 |
| 文献子类 | 期刊论文 |
| 英文摘要 | Supramolecular coordination has been developed as an efficient tool to construct a variety of discrete metallacycles and metallacages with well-defined shapes and sizes. However, its application in framework construction has been barely exploited. In this paper, we report the direct synthesis of two diamondoid frameworks from a simple tetrahedral precursor, tetra(4-(4-pyridinyl)phenyl)methane, and two linear difunctional platinum(II) ligands via one-step supramolecular coordination. Controlled by the specific angularity and geometry of the tetrahedral and linear subunits, these frameworks possess a well-defined diamondoid topology with highly regulated periodicity and three-dimensional porosity. Moreover, these rigid frameworks can be directly changed into a metallogel when prepared in DMSO at high concentrations. Interestingly, these diamondoid frameworks exhibit a cationic nature and stimuli-responsive behavior, which potentially endow them with the selective adsorption and controlled release for anionic dyes and drugs in aqueous environments. Thus, this study demonstrates that supramolecular coordination is a facile and efficient approach for the preparation of functional framework materials containing predesigned and well-defined supramolecular coordination assemblies as molecular skeletons. |
| 语种 | 英语 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/31551]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 作者单位 | 1.Univ Utah, Dept Chem, Salt Lake City, UT 84112 USA; 2.Univ S Florida, Dept Chem, Tampa, FL 33620 USA; 3.Yili Normal Univ, Coll Phys Sci & Technol, Xinjiang Lab Phase Transit & Microstruct Condense, Yili 835000, Peoples R China 4.Northwest Univ, Coll Chem & Mat Sci, Natl Demonstrat Ctr Expt Chem Educ, Key Lab Synthet & Nat Funct Mol Chem,Minist Educ, Xian 710069, Shaanxi, Peoples R China; 5.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Shanghai 201204, Peoples R China; |
| 推荐引用方式 GB/T 7714 | Cao, LP,Wang, PP,Miao, XR,et al. Diamondoid Frameworks via Supramolecular Coordination: Structural Characterization, Metallogel Formation, and Adsorption Study[J]. INORGANIC CHEMISTRY,2019,58(9):6268—6275. |
| APA | Cao, LP.,Wang, PP.,Miao, XR.,Duan, HH.,Wang, H.,...&Stang, PJ.(2019).Diamondoid Frameworks via Supramolecular Coordination: Structural Characterization, Metallogel Formation, and Adsorption Study.INORGANIC CHEMISTRY,58(9),6268—6275. |
| MLA | Cao, LP,et al."Diamondoid Frameworks via Supramolecular Coordination: Structural Characterization, Metallogel Formation, and Adsorption Study".INORGANIC CHEMISTRY 58.9(2019):6268—6275. |
入库方式： OAI收割
来源：上海应用物理研究所
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