Electrochemical behaviors and electrolytic separation of Th(IV) and Ce(III) in ThF4-CeF3-LiCl-KCl quaternary melt
文献类型：期刊论文
| 作者 | Wang, XB; Zheng, HY; Xu, QH; Zhu, TJ; Jiang, F; She, CF; Wang, CY; Cong, HX; Gong, Y; Huang, W |
| 刊名 | SEPARATION AND PURIFICATION TECHNOLOGY
 |
| 出版日期 | 2019 |
| 卷号 | 210期号:-页码:236—241 |
| 关键词 | LIF-NAF-KF LICL-KCL THORIUM ELECTRODEPOSITION FLUORIDES URANIUM |
| ISSN号 | 1383-5866 |
| DOI | 10.1016/j.seppur.2018.08.013 |
| 文献子类 | 期刊论文 |
| 英文摘要 | The extraction and recycle of thorium is an essential step in the thorium-uranium closed fuel cycle designed for Thorium-based Molten Salt Reactor system (TMSR), and the separation of thorium from FPs especially lanthanides is a key issue in the thorium recovery. In this paper, the electrochemical behaviors of Th(IV) and Ce(III) on Mo electrode were studied by cyclic voltammetry (CV) and chronopotentiometry (CP) techniques at 773 K in ThF4(3 wt%)/CeF3(0.3 wt%)-LiCl-KCl ternary melt and CeF3(0.3 wt%)-ThF4(3 wt%)-LiCl-KCl quaternary melt, respectively. The reduction peaks of Th(IV)/Th(0) and Ce(III)/Ce(0) were at 1.83 V and 2.21 V (vs. Ag/AgCl) in the respective ternary melt, respectively, which were same with the values in the quaternary melt; however, the oxidation peaks in the CeF3-ThF4-LiCl-KCl melt shifted negatively about 0.1 V. Pulsed potential electrolysis of quaternary melt revealed that 98.9% of Th(IV) can be electrochemical separated from the melt with almost all cerium remaining in the melt, based on the inductively coupled plasma atomic emission spectrometer (ICP-AES) results. |
| 语种 | 英语 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/31588]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 作者单位 | 1.Chinese Acad Sci, Ctr Excellence TMSR Energy Syst, Shanghai 201800, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China; 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China; |
| 推荐引用方式 GB/T 7714 | Wang, XB,Zheng, HY,Xu, QH,et al. Electrochemical behaviors and electrolytic separation of Th(IV) and Ce(III) in ThF4-CeF3-LiCl-KCl quaternary melt[J]. SEPARATION AND PURIFICATION TECHNOLOGY,2019,210(-):236—241. |
| APA | Wang, XB.,Zheng, HY.,Xu, QH.,Zhu, TJ.,Jiang, F.,...&Li, QN.(2019).Electrochemical behaviors and electrolytic separation of Th(IV) and Ce(III) in ThF4-CeF3-LiCl-KCl quaternary melt.SEPARATION AND PURIFICATION TECHNOLOGY,210(-),236—241. |
| MLA | Wang, XB,et al."Electrochemical behaviors and electrolytic separation of Th(IV) and Ce(III) in ThF4-CeF3-LiCl-KCl quaternary melt".SEPARATION AND PURIFICATION TECHNOLOGY 210.-(2019):236—241. |
入库方式： OAI收割
来源：上海应用物理研究所
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