Framework disorder and its effect on selective hysteretic sorption of a T-shaped azole-based metal-organic framework
文献类型：期刊论文
| 作者 | Wang, SJ; Wei, ZW; Zhang, JY; Jiang, L; Liu, DX; Jiang, JJ; Si, R; Su, CY |
| 刊名 | IUCRJ
 |
| 出版日期 | 2019 |
| 卷号 | 6期号:-页码:85—95 |
| 关键词 | SECONDARY BUILDING UNITS CARBON-DIOXIDE CAPTURE COORDINATION POLYMER BREATHING BEHAVIOR HYDROGEN STORAGE CO2 UPTAKE PORE-SIZE ADSORPTION PROPERTIES GAS-ADSORPTION SITES |
| ISSN号 | 2052-2525 |
| DOI | 10.1107/S2052252518015749 |
| 文献子类 | 期刊论文 |
| 英文摘要 | Metal-organic frameworks with highly ordered porosity have been studied extensively. In this paper, the effect of framework (pore) disorder on the gas sorption of azole-based isoreticular Cu(II) MOFs with rtl topology and characteristic 1D tubular pore channels is investigated for the first time. In contrast to other isoreticular rtl metal-organic frameworks, the Cu(II) metal-organic framework based on 5-(1H-imidazol-1-yl)isophthalate acid has a crystallographically identifiable disordered framework without open N-donor sites. The framework provides a unique example for investigating the effect of pore disorder on gas sorption that can be systematically evaluated. It exhibits remarkable temperature-dependent hysteretic CO2 sorption up to room temperature, and shows selectivity of CO2 over H-2, CH4 and N-2 at ambient temperature. The unique property of the framework is its disordered structure featuring distorted 1D tubular channels and DMF-guest-remediated defects. The results imply that structural disorder (defects) may play an important role in the modification of the performance of the material. |
| 语种 | 英语 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/31642]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 作者单位 | 1.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Shanghai 201204, Peoples R China 2.Sun Yat Sen Univ, Lehn Inst Funct Mat, MOE Lab Bioinorgan & Synthet Chem, Guangzhou 510275, Guangdong, Peoples R China; |
| 推荐引用方式 GB/T 7714 | Wang, SJ,Wei, ZW,Zhang, JY,et al. Framework disorder and its effect on selective hysteretic sorption of a T-shaped azole-based metal-organic framework[J]. IUCRJ,2019,6(-):85—95. |
| APA | Wang, SJ.,Wei, ZW.,Zhang, JY.,Jiang, L.,Liu, DX.,...&Su, CY.(2019).Framework disorder and its effect on selective hysteretic sorption of a T-shaped azole-based metal-organic framework.IUCRJ,6(-),85—95. |
| MLA | Wang, SJ,et al."Framework disorder and its effect on selective hysteretic sorption of a T-shaped azole-based metal-organic framework".IUCRJ 6.-(2019):85—95. |
入库方式： OAI收割
来源：上海应用物理研究所
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